Organosamarium catalysts for the hydroamination of olefins

Details Organosamarium catalysts for the hydroamination of olefins Organosamarium catalysts for the hydroamination of olefins

1990-03-13

1992-05-05

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

546184, 564485, 548485, C07D20706, C07D295023, C07D 2402, C07D20904

Patent

active

051109484

ABSTRACT:
The reaction of a samarium catalyst [.eta..sup.5 --(CH.sub.3).sub.5 C.sub.5 ].sub.2 Sm(THF).sub.2 with amino-olefins provides a straightforward route to a heterocyclic compound. Alternatively, the reaction of olefins with the samarium catalyst in the presence of an amine results in an aminoalkane.

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