Chemistry: natural resins or derivatives; peptides or proteins; – Lignins or derivatives – Heavy metal – aluminum – silicon or phosphorus containing
Patent
1987-12-14
1989-08-01
Sutto, Anton H.
Chemistry: natural resins or derivatives; peptides or proteins;
Lignins or derivatives
Heavy metal, aluminum, silicon or phosphorus containing
C07F 902
Patent
active
048534650
DESCRIPTION:
BRIEF SUMMARY
FIELD OF THE INVENTION
The invention relates to organophilic derivatives of complex phenolic compounds, to methods for their manufacture, and to their use in oil base well working fluids.
BACKGROUND OF THE INVENTION
In the drilling of wells for oil and gas by the rotary method, it is common to use a circulating fluid which is pumped down to the bottom of the well through a drill pipe, where the fluid emerges through ports in the drilling bit. The fluid rises to the surface in the annular space between the drill pipe and the walls of the hole, and at the surface it is treated to remove cuttings and the like to prepare it for recirculation into the drill pipe. The circulation is substantially continuous while the drill pipe is rotated.
The present invention pertains to oil base drilling fluids or oil base muds which includes water-in-oil (invert) emulsions as well as oil base fluids containing only small amounts or no emulsified water. An important feature of well working fluids of the class described is their ability to resist filtration. In most instances, when they are in actual use, whether as drilling fluids, packer fluids, fracturing or completion fluids, the well working fluid is in contact with a more or less permeable formation, such as, for example, sandstone, sandy shale and the like, with an effective balance of pressure such that the fluid tends to be forced into the permeable formation. When a well working fluid is deficient in its ability to resist filtration, then the solids in the fluid are held back by the permeable formation and build up as a filter cake or sludge on its surfaces, while the liquid per se of the well working fluid filters into the permeable formation. The filter cake or sludge thus formed is generally very undesirable. Moreover, the loss of oil to the formation is very expensive, not only because of the cost of the oil itself, but also due to the cost of maintaining the properties and composition of the fluid.
Various additives have been used or suggested for use as fluid loss additives to prevent or decrease this loss of fluid by filtration from oil base muds. Some of the first materials used for this purpose were asphalt and various modified asphaltic materials. The following patents disclose various amine derivatives of various polyphenolic compounds for use as fluid loss control additives (hereinafter sometimes referred to as FLCA) for oil muds: U.S. Pat. Nos. 3,168,475 Jordan et al.; Jordan et al. 3,281,458; Beasley et al. 3,379,650; Cowan et al. 3,232,870; Cowan et al. 3,425,953; Andrews et al. 3,494,865; Andrews et al. 3,671,427, Andrews et al. 3,775,447; Kim 3,538,071; Kim 3,671,428; Cowan 4,421,655; Connell et al. 4,501,672; and Frost European Patent Application 049,484.
As noted in the examples in the aforementioned patents, the amount of the organic amine or amide compounds reacted with the polymeric phenolic compounds disclosed is quite high, generally of the order of 75%-100% or more, based on the weight of the polymeric phenolic compound, although amounts from 20% to 200% are disclosed to be useful. Most of these FLCA possess poor dispersibility in we1l working f1uids unless elaborate procedures are undertaken, such as the addition of a dispersant, heating, agitating under high shear or for extended periods of time, drying under low temperature conditions, flushing, preparation in oleaginous liquids, and the like. Moreover, the amine and amide compounds are relatively expensive to prepare and/or purchase, and thus these FLCA are quite expensive to produce.
SUMMARY OF THE INVENTION
We have now found that organophilic derivatives of polyphenolic materials can be prepared by reaction of the polyphenolic compound with a phosphatide, preferably commercial lecithin. These phosphatide/polyphenolic compound adducts are organophilic, relatively inexpensive to prepare, and thus are excellent low-cost fluid loss additives for oil based working fluids.
PREFERRED EMBODIMENTS OF THE INVENTION
The novel FLCA of this invention comprises an organophilic material whic
REFERENCES:
patent: 3671428 (1972-06-01), Kim
patent: 4421655 (1983-12-01), Cowan
Cowan Jack C.
Granquist Victor M.
House Roy F.
House Roy F.
Sutto Anton H.
Venture Chemicals, Inc.
LandOfFree
Organophilic polyphenolic acid adducts does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Organophilic polyphenolic acid adducts, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Organophilic polyphenolic acid adducts will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-132369