Organopalladium approaches to prostaglandins

Details Organopalladium approaches to prostaglandins Organopalladium approaches to prostaglandins

1987-11-16

1989-03-21

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

562502, C07C17700

Patent

active

048144908

ABSTRACT:
A prostaglandin precursor is made by reacting a bicyclic olefin with an alkyl (acetoxymercurio) carboxylate, a palladium salt, and an 1-alken-3-one to provide a keto ester bicycloheptane.

REFERENCES:
patent: 3418102 (1968-12-01), Richter
patent: 3492330 (1970-01-01), Trecker et al.
patent: 4113755 (1978-09-01), Larock
patent: 4351949 (1982-09-01), Larock
patent: 4436934 (1984-03-01), Larock
patent: 4520207 (1985-05-01), Larock
patent: 4563537 (1986-01-01), Larock
Larock et al., J. Org. Chem. 52, 1364 (1987).

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