Organometallic solutions for forming oxide superconducting films

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505734, 505735, 10628718, 10628723, 427226, 427 62, 427 63, 501152, 556 28, C09K 300

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050011103

ABSTRACT:
A solution for forming a superconductive thin film prepared by dissolving a mol of a compound selected from group A consisting of alkoxides and alkoxyalkoxides of a rare earth metal element; b mol of a compound selected from group B consisting of alkoxides and alkoxyalkoxides of Ba, Sr and Ca; and c mol of a compound selected from group C consisting of alkoxides and alkoxyalkoxides of Cu in e liter of a compound selected from group E, a solvent selected from alcohols together with d mol of a compound selected from group D for inhibiting hydrolysis action such as an amine, a ketone and a glycol, such that the following relationships:

REFERENCES:
patent: 4636440 (1987-01-01), Jada
patent: 4668299 (1987-05-01), Nanao et al.
Shibata et al, "Superconducting Oxides by the Sol-Gel Method Using Alkoxides", Jpn. J. Appl. Phys., vol. 27(1), Jan. 1988, L53-54.
Kramer et al., "Preparation of Thin Film YBa.sub.2 Cu.sub.3 O.sub.6+x Ceramic Superconductors by the Sol-Gel Process", MRS, vol. 99, Nov. 1987, pp. 323-326.
Uchikawa et al, "Fabrication of YBa.sub.2 Cu.sub.3 O.sub.7-x Fibers Using the Modified Sol-Gel Method", MRS ed., Capone II, Apr. 1988, pp. 89-92.
Cima et al, "Ba.sub.2 YCu.sub.3 O.sub.6.9 Powder Preparation by Sol-gel emulsion Technique", MRS, vol. 99, Nov. 1987, pp. 241-244.

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