Organometallic polymer

Details Organometallic polymer Organometallic polymer

1987-11-10

1989-10-10

Anderson, Harold D.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

From heavy metal or aluminum reactant having at least one...

528397, C08G 7900, C08G 8300

Patent

active

048733040

ABSTRACT:
Metallocene polymers characterized as being in a stacked configuration where the monomeric units are constrained to interact with one another across their cofacial cyclopentadienyl ring surfaces, and having the general structure ##STR1## where M represents the metal and n is an integer of 2 or greater. The preparative method involves the coupling reaction between a zincated metallocene and a dihalogen-substituted aromatic, in the presence of a catalyst. The mixture is refluxed, and the resultant polymer is taken up in organic solvent, washed, dried, separated and purified.

REFERENCES:
patent: 3437634 (1969-04-01), Neuse
patent: 3504052 (1970-03-01), Neuse et al.
Lee, M.-T. et al., Organometallics 3:539-547, 1985.
Katz, T. J. and J. Pesti, J. Am. Chem. Soc. 104:346-347, 1982.
Neuse, E. W. and L. Bednarik, Transition Metal Chemistry 4:87-94, 1979.
Felkin, H. and G. Swierczewski, Tetrahedron 31:2735-2748, 1975.
Sudhakar, A., T. J. Katz and B.-W. Yang, J. Am. Chem. Soc. 108:2790, 1986.

Affiliated with

Also associated with

Rating

Organometallic polymer does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Organometallic polymer, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Organometallic polymer will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1958277