Organometallic iridium compound, process for producing the...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C427S252000

Reexamination Certificate

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10568388

ABSTRACT:
An organometallic iridium compound having low melting point, excellent vaporization characteristic and low film formation temperature on a substrate, a process for producing the compound, and a process for preparing iridium-based films using the organometallic compound are provided.The organometallic iridium compound represented by the formula (1)(example of specific compound: (ethylcyclopentadienyl)bis(ethylene)iridium) is obtained by reacting a compound represented by the formula (4)with a compound represented by the formula (2) or (3)An iridium-based film is prepared using the compound as a precursor. In the formulae, R1represents hydrogen atom or a lower alkyl group; R2represents a lower alkyl group; X represents a halogen atom; and M represents an alkali metal.

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M. Dziallas, et al., Basische Metalle LXII Darstellung Und Reaktionen Dermetall-Basen C5H5Ir (OLEFIN) PPr3Und C5H5Ir (OLEFIN)2, Journal of Organometallic Chemistry, 1987, vol. 330, No. 1-2, pp. 207-219.
A. L. Onderdelinden, et al., “Chloro- and Bromo- (alkene)iridium (I) Complexes”, Inorganica Chimica Acta, 6:3, Sep. 1972.

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