Organometallic intercalates of metal chalcogenohalides

Details Organometallic intercalates of metal chalcogenohalides Organometallic intercalates of metal chalcogenohalides

1979-01-02

1980-06-10

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

250272, 2504751, 252 497, 252431R, 260429CY, 2604293, 2604385R, 260439CY, 429218, 429221, C07F 728

Patent

active

042072450

ABSTRACT:
A new group of materials comprises intercalates of organometallic compounds in layered structures of metal chalcogenohalides. The organometallic intercalates are represented by the general formula MX.sub.a Y.sub.b [Z].sub.c, where M is at least one metal selected from the group consisting of titanium, vanadium, chromium, manganese, iron and indium, X and Y are members of the group consisting of chalcogenides and halides, "a" and "b" each range from 0 to 2, with the sum of "a" and "b" being substantially equal to about 2, Z is an organometallic "sandwich" compound with parallel carbocyclic rings and a first ionization potential less than about 7 eV and "c" ranges from about 0.1 to 0.2.

REFERENCES:
patent: 3673015 (1972-06-01), Sollott et al.
patent: 3688109 (1972-08-01), Gamble
patent: 3980684 (1976-09-01), Dines
patent: 4049887 (1977-09-01), Whittingham
patent: 4094893 (1978-06-01), Dines
patent: 4119655 (1978-10-01), Hulme
Clement et al, Inorganic Chemistry, 17 2754-2758 (1978).

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