Organometallic derivatives of group IIIA and process for their p

Organic compounds -- part of the class 532-570 series – Organic compounds – Aluminum containing

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556 1, 556187, C07F 506

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056022697

ABSTRACT:
New organometallic derivatives of group IIIA are described having general formula M(C.sub.6 F.sub.5).sub.3 wherein M is a metal of group IIIA selected from aluminium, gallium and indium.
The above derivatives are prepared by exchange reaction between a metal alkyl MR.sub.3 with an organometallic derivative of boron having the formula B(C.sub.6 F.sub.5).sub.3.

REFERENCES:
Journal of Organometlic Chemistry, vol. 441, No. 3, pp. 363-371, 1992, K. Ludovici, et al., "Synthesis and Properties of Pentafluorophenylgallium Derivatives. The Preparation of Tris(Pentafluorophenyl)Gallium and Its Adducts, and of Bis(Pentafluorophenyl)Gallium Bromide, Pentafluorophenylgallium Dibromide, and Tetrabutylammonium Tetrakis(Pentafluorophenyl)Gallate".
Chemical Abstracts, vol. 75, No. 19, An 118363X, 1971.
Chemical Abstracts, vol. 74, No. 23, AN 125769S, Jun. 7, 1971.

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