Organometallic compounds

Details Organometallic compounds Organometallic compounds

1999-01-25

2000-10-31

Lambkin, Deborah C.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

548518, 549 59, 549479, C07D21304, C07D20700, C07D40900, C07D30702

Patent

active

061405035

ABSTRACT:
A compound consisting of three aromatic moieties respectively bonded to a methyl carbocation, and a counterion; wherein each of the three aromatic moieties is optionally substituted with an electron-donating group, at least one of the three aromatic moieties is bonded to a metal complex moiety, either directly or through a linker, and the methyl carbocation, the aromatic moieties, the metal complex moiety, and the linker form a conjugated system.

REFERENCES:
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patent: 5453522 (1995-09-01), Davis et al.
Bildstein et al., Cationic and Neutral [4]-Cumulenes C=C=C=C=C with Five Cumulated Carbons and Three to Four Ferrocenyl Termini, Organometallics 1998, 17, 2414-2424.
Chen et al., "Synthesis and Linear Optical Sepctroscopy of Thioflavylium Near-Infrared Absorbing Dyes", Adv. Mater. 1995, 7, No. 12, 1030-1033.
Heck et al., "Bimetallic Sandwich-Like Complexes as Novel NLO-Chromophores", SPIE, 1997, vol. 3147, 53-61.
Lee et al., "Dinuclear Complexes Containing Ferrocenyl and Oxomolybdenum (V) Groups Linked by Conjugated Bridges: A new Class of Electrochromic . . . ", Chem. Mater. 1998, 10, 3272-3274.
Tolbert et al., "Bis(ferrocenyl)polymethine Cations. A Prototype Molecular Wire with Redox-Active End Groups", J. Am. Chem. Soc., 1995, 117, 12891-12892.

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