Organometallic compound, catalyst for polymerization of...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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C502S103000, C502S117000, C502S152000, C526S133000, C526S160000, C526S169100, C526S171000, C526S281000

Reexamination Certificate

active

07902109

ABSTRACT:
An organometallic compound obtained by mixing following (a), (b) and (c): (a) a neutral organopalladium complex that has a palladium atom and two organic ligands each having at least three carbon atoms participating in a bond to the palladium atom; (b) an organophosphorus compound having one phosphorus atom; and (c) a salt comprising: an anion having no unshared electron pair in a central atom; and a counter-cation. And a process for producing a norbornene compound polymer, the process comprising: subjecting at least one norbornene compound represented by formula (A) as defined in the specification to polymerization reaction in a presence of an organometallic complex catalyst produced by mixing compound (a) and compound (d) described in the specification.

REFERENCES:
patent: 4659843 (1987-04-01), Binger et al.
patent: 6825307 (2004-11-01), Goodall
patent: 7-304834 (1995-11-01), None
patent: 2006-052347 (2006-02-01), None
patent: WO 00/20472 (2000-04-01), None
patent: WO 2005/019277 (2005-03-01), None
patent: WO 2005-054312 (2005-06-01), None
Form PCT/ISA/210 (International Search Report) dated Aug. 1, 2006.
Form PCT/ISA/237 (Written Opinion of the International Searching Authority) dated Aug. 1, 2005.
Kumiko Matsushita et al., “Polymerization of Norbornene and Derivatives Catalyzed by Ni and Pd Complexes”, Nihon University, OM Chem-Tech Co., Ltd., IPA-019, Mar. 11, 2005, 3 pages, The 85th Spring Meeting Drafts of the Chemical Society of Japan, (cited in International Search Report, Written Opinion and on pp. 3-4 of the specification).
Joice P. Mathew et al., “(img id="CUSTOM-CHARACTER-00001" he="3.13mm" wi="1.44mm" file="US07902109-20110308-P00001.TIF" alt="custom character" img-content="character" img-format="tif" ?3-Allyl)Palladium (II) and Palladium (II) Nitrile Catalysts for the Addition Polymerization of Norbornene Derivatives With Functional Groups”, Macromolecules, 1996, vol. 29, pp. 2755-2763, American Chemical Society (cited on p. 2 of the specification).
B. S. Heinz et al., “Poly(Norbornene Carboxylic Acid Ester)S: Synthesis and Properties”, Acta Polymer., 1997, vol. 48, pp. 385-391, VCH Verlagsgesellschaft mbH, Weinheim (cited on p. 2 of the specification).
Cecily Andes et al., “The Copolymerization of Functionalized Norbornenes and the Comparison of Reactivy Ratios Using Various Palladium Catalysts”, Polymer Preprints, 2002, vol. 43, No. 2, pp. 963-964 (cited on pp. 2-3 of the specification).
Polymer Preprints, Japan, 2005, vol. 54, No. 1, p. 277, 1Pe037 (cited on pp. 4-5 of the specification).

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