Organometallic complexes as phosphorescent emitters in...

Stock material or miscellaneous articles – Composite – Of inorganic material

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C428S917000, C313S504000, C313S506000, C257S102000, C257S103000

Reexamination Certificate

active

06902830

ABSTRACT:
Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

REFERENCES:
patent: 4455506 (1984-06-01), Ayyagari et al.
patent: 4539507 (1985-09-01), VanSlyke et al.
patent: 4758765 (1988-07-01), Mitsumori
patent: 4769292 (1988-09-01), Tang et al.
patent: 4950950 (1990-08-01), Perry et al.
patent: 5128587 (1992-07-01), Skotheim et al.
patent: 5203974 (1993-04-01), Kokado et al.
patent: 5231329 (1993-07-01), Nishikitani et al.
patent: 5247190 (1993-09-01), Friend et al.
patent: 5294810 (1994-03-01), Egusa et al.
patent: 5294870 (1994-03-01), Tang et al.
patent: 5439794 (1995-08-01), Barton
patent: 5457565 (1995-10-01), Namiki et al.
patent: 5504183 (1996-04-01), Shi et al.
patent: 5540999 (1996-07-01), Yamamoto et al.
patent: 5554220 (1996-09-01), Forrest et al.
patent: 5601903 (1997-02-01), Fujii et al.
patent: 5663573 (1997-09-01), Epstein et al.
patent: 5674597 (1997-10-01), Fujii et al.
patent: 5698048 (1997-12-01), Friend et al.
patent: 5703436 (1997-12-01), Forrest et al.
patent: 5707745 (1998-01-01), Forrest et al.
patent: 5756224 (1998-05-01), Bōrner et al.
patent: 5757026 (1998-05-01), Forrest et al.
patent: 5757139 (1998-05-01), Forrest et al.
patent: 5811833 (1998-09-01), Thompson
patent: 5811834 (1998-09-01), Tamano et al.
patent: 5834130 (1998-11-01), Kido
patent: 5834893 (1998-11-01), Bulovic et al.
patent: 5840897 (1998-11-01), Kirlin et al.
patent: 5844363 (1998-12-01), Gu et al.
patent: 5861219 (1999-01-01), Thompson et al.
patent: 5874803 (1999-02-01), Garbuzov et al.
patent: 5917280 (1999-06-01), Burrows et al.
patent: 5932895 (1999-08-01), Shen et al.
patent: 5953587 (1999-09-01), Forrest et al.
patent: 5981306 (1999-11-01), Burrows et al.
patent: 5986268 (1999-11-01), Forrest et al.
patent: 5986401 (1999-11-01), Thompson et al.
patent: 5989738 (1999-11-01), Haase et al.
patent: 5998803 (1999-12-01), Forrest et al.
patent: 6013429 (2000-01-01), Franke et al.
patent: 6013538 (2000-01-01), Burrows et al.
patent: 6013982 (2000-01-01), Thompson et al.
patent: 6030715 (2000-02-01), Thompson et al.
patent: 6045930 (2000-04-01), Thompson et al.
patent: 6046543 (2000-04-01), Bulovic et al.
patent: 6048630 (2000-04-01), Burrows et al.
patent: 6083634 (2000-07-01), Shi
patent: 6091195 (2000-07-01), Forrest et al.
patent: 6091382 (2000-07-01), Shioya et al.
patent: 6097147 (2000-08-01), Baldo et al.
patent: 6111902 (2000-08-01), Kozlov et al.
patent: 6125226 (2000-09-01), Forrest et al.
patent: 6160828 (2000-12-01), Bulovic et al.
patent: 6242115 (2001-06-01), Thomson et al.
patent: 6303238 (2001-10-01), Thompson et al.
patent: 6337102 (2002-01-01), Forrest et al.
patent: 6358631 (2002-03-01), Forrest et al.
patent: 6524727 (2003-02-01), Kathirgamanathan
patent: 6656608 (2003-12-01), Kita et al.
patent: 6670645 (2003-12-01), Grushin et al.
patent: 2002/0034656 (2002-03-01), Thompson et al.
patent: 0 704 915 (1996-04-01), None
patent: 3-289090 (1991-12-01), None
patent: 96/19792 (1996-06-01), None
patent: 97/33296 (1997-09-01), None
patent: 97/48115 (1997-12-01), None
patent: 97/48139 (1997-12-01), None
patent: 98/50989 (1998-11-01), None
patent: WO 98/58037 (1998-12-01), None
patent: 02/02714 (2002-01-01), None
patent: 02/15645 (2002-02-01), None
Lamansky et al.,Optical Properties of Pt(II)Cyclometalated Complexes in Polymer Matrices, Preparation and Potential Uses in OLEDs, Abstracts of Papers,Part 1, 217thACS National Meeting, Anaheim, CA (Mar. 21-25, 1999).
Chemistry.ORG, The Website of the American Chemical Society, Internet Schedule of 217thACS National Meeting, (Mar. 21-25, 1999); printed on Jul. 22, 2003 at http://chemistry.org/portal/PersonalScheduler/SearchResults.isp?refineMode=Y&adySearch=O.
Ching Tang, “Brightness on Display”, OE Magazine, The Monthly Publication of SPIE—The International Society for Optical Engineering, Feb. 2001. (page numbers not given).
P.F. Schewe et al, “Electrophosphorescence gets the green light”, Physics News Update Number 437, Story #2, The American Institute of Physics Bulletin of Physics News, Jul. 2, 1999.
Y. Ma, et al., “High Luminescence Gold (I) and Copper (I) Complexes with a Triplet Excited State for Use in Light-Emitting Diodes”, Advanced Materials 1999, 11, No. 10, pp. 852-857. (no month).
G. Calogero, et al., “Absorption spectra, luminescence properties, and electrochemical behavior of cyclometalated Iridium (III) and Rhodium (III) complexes with a Bis(pyridyl)triazole ligand”, Inorg. Chem. 1995, 34, pp. 541-545. (no month).
G. Di Marco, et al., “Luminescent mononuclear and dinuclear Iridium (III) cyclometalated complexes immobilized in a polymeric matrix as solid-state oxygen sensors”, Anal. Chem. 70, pp. 5019-5023, published on Web Oct. 24, 1998.
C. Berg-Brennan, et al., “Luminescent ruthenium polypyridyl complexes containing pendant pyridinium acceptors”, Inorg. Chem. 1996, 35, pp. 3719-3722. (no month).
Y. Ma, et al., “Electroluminescence from triplet metal-ligand charge-transfer excited state of transition metal complexes”, Synthetic Metals 94 (1998), pp. 245-248. (no month).
H.F. Wittmann, et al., “Optical spectroscopy of platinum and palladium containing poly-ynes”, J. Chem. Phys., vol. 101, No. 4, pp. 2693-2698, Aug. 15, 1994.
M.A. Baldo, et al., “Phosphorescent materials for application to organic light emitting devices”, Pure Appl. Chem., vol. 71, No. 11, pp. 2095-2106, 1999. (no month).
G. DiMarco, et al., “A Luminescent Iridium(III) Cyclometallated Complex Immobilized in a Polymeric Matrix as a Solid-State Oxygen Sensor”, Advanced Materials, vol. 8, pp. 576-580, Jul. 1996.
J.N. Demas, et al., “Design and Applications of Highly Luminescent Transition Metal Complexes”, Analytical Chemistry, vol. 63, No. 17, pp. 829-837, Sep. 1, 1991.
K. Vinodgopal, et al., “Photochemistry of Ru(bpy)2(dcbpy)2+ on AI203 and TiO2 Surfaces. An Insight into the Mechanism of Photosensitization”, J. Phys. Chem. 1995, 99, 10883-10889. (no month).
R. Holmlin et al., “Os(Phen)2dppz2+ in Photoinduced DNA-Mediated Electron Transfer Reactions”, J. Am. Chem. Soc. 1996 118, pp. 5236-5244. (no month).
S. W Depp and W. E. Howard, “Flat Panel Displays,” Scientific American 90 (Mar. 1993).
D. Z. Garbuzov et al., “Photoluminescence Efficiency and Absorption of Aluminum Tris-Quinolate (Alq3) Thin Films,” 249Chemical Physics Letters,433-437 (Feb. 1996).
C. E. Johnson et al., “Luminescent Iridium (I), Rhodium (I), and Platinum (II) Dithiolate Complexes,” 105Journal of the American Chemical Society1795-1802 (1983). (no month).
Hosokawa et al., “Highly efficient blue electroluminescence from a distyrylarylene emitting layer with a new dopant,” 67Appl. Phys. Lett.3853-3855 (Dec. 1995).
Adachi et al., “Blue light-emitting organic electroluminescent devices,” 56Appl. Phys. Lett.799-801 (Feb. 1990).
C. C. Wu et al., “Integrated three-color organic light-emitting devices,” 69Appl. Phys. Lett.3117-3119 (Nov. 1996).
H. Vestweber et al., “Electroluminescense from polymer blends and molec

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Organometallic complexes as phosphorescent emitters in... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Organometallic complexes as phosphorescent emitters in..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Organometallic complexes as phosphorescent emitters in... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3513466

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.