Organically clean biomass fuel

Details Organically clean biomass fuel Organically clean biomass fuel

2004-01-13

2004-11-16

Toomer, Cephia D. (Department: 1714)

Fuel and related compositions

Consolidated solids

C044S590000, C044S606000

Reexamination Certificate

active

06818027

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an organically clean biomass fuel from a mixture of finely ground wood chips, bark, sawdust, wood charcoal powder or other any other cellulosic products that are dried and then moisturized by vegetable oil and/or vegetable alcohol. The organically clean biomass fuel is clean burning and non-toxic.
2. Description of Related Art
U.S. Pat. No. 5,244,472 (the '472 patent) reveals the preparation of a chemically dried cellulosic fuel. Wood chips, bark, sawdust or other cellulosic products are dried and impregnated with vegetable oil to provide a clean burning, non-toxic fuel for lighting or starting charcoal. To achieve this, the cellulosic products are ground between ¼ and 2 inches in diameter and immersed in hot oil at between 325° F. and 375° F. (163° C.-191° C.). Moisture within the cellulosic products evaporates and replaced by the hot oil. Contaminants in the hot oil may be released upon heating.
There are over 350 species of oleaginous, or oil-producing plants and thousands of sub-species. Two types of oil presses are used in both small and large scale vegetable oil processing. The most common type of oil press is the screw press. This press uses a large scale diameter screw inside a metal housing. The oil seed is fed into the top of the press and falls into the churning screw. As the seed is churned into a mash by turning threads of the screw, the oil is squeezed from the meal, or cake. The protein cake from the oilseed oozes from the side of the press and the vegetable oil dribbles from the bottom of the press.
Screw presses are available in sizes ranging from table-top models that produce 8 kilograms of seed per hour (2 liters of oil) to industrial models which can produce 4,000 kilograms of oil per day. Screw presses are available in electrical and Diesel powered models. Screw presses tend to be slow. A ram press is more efficient oil press design. This press uses a hydraulic piston inside of a cylinder to crush the oilseed. Ram presses can be powered by hand, by an electric motor, or by a Diesel engine.
After a vegetable oil is pressed, it is left to settle for a few days in horizontal settling tank. The vegetable gums and pieces of meal cake settle to the bottom of the tank. If it is to be used as a fuel, it should be pumped through a series of filters. Usually it is a four stage process, starting with 150 micron mash, then 70, then 25 and lastly a 10 micron fuel filter.
An ester is a hydrocarbon chain that, for certain compounds such as alcohol or amine, will bond with another molecule. A vegetable oil molecule is made of three esters attached to a molecule of triglycerin. Vegetable oil is also called glycerol esters. About 20% of a vegetable oil molecule is glycerin. Glycerin is also called glycerine. Glycerin makes vegetable oil thick and sticky. To transform vegetable oil into fuel, vegetable oil must go through the process of transesterification. Transesterefication is the transformation of one type ester into another type of ester. The esters in vegetable oil are separated from the glycerin, the glycerin is replaced with alcohol. Either ethanol alcohol or methanol alcohol can be used. Ethanol is alcohol made from grain. Methanol is an alcohol that can be made from wood or coal. Methanol produces more stable biodiesel reactions. However, methanol is an aggressive alcohol which dissolves rubber, can be fatal is swallowed, and requires extreme caution when handled.
The cloud point is point at which vegetable oil appears cloudy because wax crystals form in the vegetable oil −60-25 F (16 and −4 C). The pour point—oil ceased to move through pipes and tubes ~−10 F. The gel point—oil will become the consistency of petroleum jelly ~−20 F. To overcome these obstacles, winterizing agents, anti-gel formula and flow—improver additive can be used. The flash point (ignition temperature) is above 300 F. The energy capacity is approximately 30 megajoules of energy per kilogram of the vegetable oil.
Emission Characteristics of vegetable oil as a fuel source as compared to regular fuel oil include the following:
Produces no sulfur dioxide (SO2)
No net carbon dioxide (CO2). “Net” in the sense that for each kilogram of fuel burned, up to three kilograms of carbon dioxide are consumed by the plants.
Less soot by 50%
Less carbon monoxide (CO) by 50%
Less hydrocarbon (HC) by 40%
Less polycyclic aromatic hydrocarbons (PAHs), specifically:
Phenanthren by 97%
Benzofloroanthen by 56%
Benzaperyren by 71%
Aldehydes by 15%
For purposes of this application, the phrase “vegetable alcohol” will refer to ethanol alcohol, methanol alcohol, a combination of each, or other forms of alcohol derived from vegetable oil after undergoing transesterification.
The inventor has a patent application pending on the manufacture and composition of wood charcoal, namely, U.S. Ser. No. 058677, publication no. 20020148716 entitled Portable Kiln for Making Charcoal from Forestry Wood Waste. The contents of that patent application are incorporated by reference.
The inventor has found that a moisture laden cellulosic product may be ground only to a certain size in a conventional grinder. This is because the moisture causes the cellulosic product to become sticky and thus cling to the surfaces of the grinder. Such may explain why the '472 patent only proposes grinding at the lower range to ¼ inch diameter.
Granular cellulose powder is available commercially and used in the plastic, welding electrode, rubber and filter industries as commercialized by Micro-Technik GmbH & Co. KG. It offers granular cellulose powder, such as those with the following characteristics:
Grade-402-100
Analysis:
from . . . to
Method
Cellulose content (atro)
min. 99%
Statement by producer
&agr;-content
88-90%
Statement by producer
Water content
<6%
4 h drying at 105° C.
DP
600-1400
Cuoxam method by Staudinger
pH Value in a 5% slurry
5-7,5
Potentiometrically
Ash content
0.1-0.2%
Glow in a platinum crucible
Bulk density
150-180 g/l
Filling up a 0.5 l graduated
cylinder
Fiber length
max. 100 &mgr;m
By mikroscope
Fiber diameter
ca. 20 &mgr;m
By mikroscope
Grade: 402-2b:
Analysis:
from . . . to
Method
Water content
<6%
4 h drying at 105° C.
&agr;-Content
88-90%
Statement by producer
pH Value in a 5%
5-7.5
Potentiometrically
slurry
Ash content
max. 0.5%
Glow in a platinum crucible
Bulk density
180-300 g/l
Filling up a 0.5 l graduated
cylinder
Water Content
<6%
4 h drying at 105° C.
DP
600-1400
Cuoxam method by Staudinger
pH Value in a 5%
4.9-5.3
Potentiometrically
slurry
Ash Content
0.1-0.2%
Glow in a platinum crucible
Resin Content
0.2-0.4%
Extraction with isopropanol
Bulk Density
>100 g/l
Filling up a 0.5 l graduated
cylinder
Acid Extract
0.5-0.8%
With 0.01 n HCl at room
temperature
Max. Fiber Length
max. 200 &mgr;m
By microscope
Fiber Diameter
about 20 &mgr;m
By microscope
Specific Surface
3500-6000 cm
2
/g
Multi-Point BET
Grade 402-1000:
Analysis
from . . . to
Method
Water Content
<6%
4 h drying at 105° C.
&agr;-Content
88-90%
According to producer
DP
600-1400
Cuoxam method by Staudinger
pH Value in a 5% slurry
4.9-5.3
Potentiometrically
Ash Content
0.1-0.2%
Glow in a platinum crucible
Resin Content
0.2-0.4%
Extraction with isopropanol
Bulk Density
80-100 g/l
Filling up a 0.5 l graduated
cylinder
Acid Extract
0.5-0.8%
With 0.01 n HCl at room
temperature
Sieve Analysis:
 >40 &mgr;m
max. 60%
Alpine air jet sieve,
>100 &mgr;m
max. 25%
10 min/sieve
>300 &mgr;m
max. 1%
>600 &mgr;m
0%
Average fibre length
100-300 &mgr;m
Grade 402-1400
Analysis
from . . . to
Method
Water Content
<6%
4 h drying at 105° C.
&agr;-Content
88-90%
According to producer
DP
600-1400
Cuoxam method by Staudinger
pH Value in a 5% slurry
4.9-5.3
Potentiometrically
Ash Content
0.1-0.2%
Glow in a platinum crucible
Resin Content
0.2-0.4%
Extraction with isopropanol
Bulk Density
50-80 g/l
Filling up a 0.5 l graduated
cylinder
Acid Extract
0.5-0.8%
With 0.01 n HCl at room
temperature
Sieve Analysis
>100 &mgr;m
max. 5

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