Organic solvent treatment for catalysts and olefin dimerization

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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502 29, 502 31, 502 33, 502174, B01J 2118, B01J 3850, C07C 224

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049820435

ABSTRACT:
Catalyst systems, methods to improve a catalyst system, and dimerization processes therewith are provided. Catalyst systems which comprise at least one elemental alkali metal supported on an alkali metal carbonate catalyst support, are contacted with a liquid organic solvent in order to improve the isomer ratio of the desired reaction product(s) to undesired product(s).

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Dimerization of Propylene to 4-Methyl-1-Pentene with Catalysts Derived from Potassium, J. B. Wilkes, 1967, Proceedings of 7th World Petroleum Congress, vol. 5, pp. 299-309.

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