Organic reagents and process of preparing same

Details Organic reagents and process of preparing same Organic reagents and process of preparing same

1975-01-29

1978-04-18

Lilling, Herbert J.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

260 22R, 260 22C, 423 8, 423 24, 423139, 4236585, 526 20, 526 21, 526 22, 526 46, 526 481, 526 50, 526 51, 526 52, C08F21200, C08F23200, C08C 1900, B01D 1100

Patent

active

040852610

ABSTRACT:
A process for producing reagents useful in organic synthesis, for removing metal values from solutions thereof, for the capture of aldehydes, of the general formula ##STR1## wherein Z designates a recurring part (CH.sub.2 --CH--CH.sub.2 -- of a polymeric backbone of a polymer like polystyrene, of a copolymer comprising polystyrene and divinylbenzene, and butadiene, or other copolymers comprising styrene moieties; or wherein Z is the aliphatic moiety of a long-chain aralkyl compound having a terminal aryl group; or wherein Z designates alkyl; corresponding compounds wherein instead of the optionally substituted phenyl group there is present an optionally substituted naphthyl group; wherein n is an integer of from 1 to 15, and wherein Q designates a group selected from: ##STR2## wherein R designates --H, lower alkyl, aryl, which may be substituted and wherein R" designates --H, alkyl, aryl, halogen, nitro or carboxy, or ##STR3## wherein R is --H, lower alkyl, aryl (which may be substituted), R.sub.1 is --H, alkyl, aryl (which may be substituted), R.sub.2 is --H, alkyl, aryl or substituted aryl, and wherein Y is --H or a non-interfering substituent;
which comprises chemically binding an activated chemical moiety to a group Z- -, or a corresponding naphthyl-containing group, wherein Z is as defined above, according to the reaction scheme: ##STR4## wherein Q is as defined above, or a functional group which can be converted to such group after the chemical bonding; and X is --Cl or --Br.

REFERENCES:
patent: 2953547 (1960-09-01), Patterson et al.
patent: 3337479 (1967-08-01), Small
patent: 3473921 (1969-10-01), Schmuckler
patent: 3617563 (1971-11-01), Fuxelius et al.
patent: 3627708 (1971-12-01), Morse et al.
patent: 3814732 (1974-06-01), Wang
patent: 3873668 (1975-03-01), Melby
patent: 3884846 (1975-05-01), Otsuki et al.
patent: 3892689 (1975-07-01), Motani et al.
"Selective Liquid Ion Exchangers", A. L. Clingman et al., J. Appl. Chem. 13, May 1963.
Kalir et al., "Eur. J. Biochem", 42 151-156 (1974).
Fridkin et al., "Synthesis of Linear . . . Peptides", ACS 155th Apr. 1968.
Fridkin et al., Annual Review of Biochem., vol. 43, 1974.
Fridkin et al., "Use of Polymers as Chem. Reagents", JACS 90 2953 (1968).

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