Organic peroxides derived from unsaturated compounds

Details Organic peroxides derived from unsaturated compounds Organic peroxides derived from unsaturated compounds

1975-03-03

1976-05-11

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260610R, C07C30700, C07C17900

Patent

active

039563197

ABSTRACT:
New organic peroxides having the formula ##EQU1## may be prepared by reacting a monohydroperoxide selected from R.sub.5 OOH and R.sub.6 OOH with an unsaturated carbonyl compound having the formula ##EQU2## the reaction being carried out in the presence of an acid catalyst at a temperature between about -30.degree.C and +80.degree.C, the molar ratio of the carbonyl compound to the hydroperoxide being between about 1:2 and 1:10. The new organic peroxides are particularly useful for crosslinking plastomers, vulcanizing elastomers, and as initiators for radical polymerizations.

REFERENCES:
patent: 3296184 (1967-01-01), Portolani et al.
patent: 3822317 (1974-07-01), D'Angelo et al.

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