Organic nonlinear optical material and nonlinear optical element

Compositions – Light transmission modifying compositions

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252587, 385122, 385143, 359328, 359329, 549 59, 558 54, F21V 900, G02B 600, G02F 135

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active

060867949

ABSTRACT:
An organic nonlinear optical material comprising a compound having the iodonium salt structure represented by the general formula (I): ##STR1## wherein .pi..sub.1 to .pi..sub.n are the same or different and each is an atomic group having .pi. electron, I.sub.1 to I.sub.n-1 are an iodonium cation, A.sub.1 to A.sub.n-1 are the same or different and each is a counter anion for the iodonium cation, R.sup.1 and R.sup.2 are the same or different and each is a hydrogen atom or an electron donative group, and n is an integer of 2 to 4. The material has large nonlinear optical constants and shows no light absorption in the visible light region.

REFERENCES:
patent: 4087554 (1978-05-01), Haydock et al.
patent: 4607116 (1986-08-01), Yamazaki et al.
patent: 4659840 (1987-04-01), Shimizu et al.
patent: 5286901 (1994-02-01), Stang et al.
Tsugio Kitamura et al., Synthesis, pp. 945-946, "A Convenient Preparation of Diaryliodonium Triflates", Oct. 1992.
Tsugio Kitamura, et al., Bulletin of the Chemical Society of Japan, vol. 68, No. 12, pp. 3637 to 3641, Alkenyl- and Alkynyl-Substituted (p-Phenylene)Bisiodonium Ditriflates by Reactions of a (p-Phenylene)Bisiodine(III) Reagent with Alkynes and 1-Trimethylsilyl-1-Alkynes, 1995.
Peter J. Stang, et al., Tetrahedron Letters, vol. 33, No. 11, pp. 1419 to 1422, "(Dicyano)Iodonium Triflate--Novel Iodonium Species and a Versatile Reagent for the Preparation of Iodonium Salts via an Iodonium Transfer Reaction with Organostannanes", 1992.
Tsugio Kitamura, et al., Tetrahedron Letters, vol. 34, No. 25, pp. 4055 to 4058, "Novel Cyclization to Benzofurans in the Reaction of Alkylnyl(p-Phenylene)Bisiodonium Ditriflates with Phenoxide Anion", 1993.
Peter J. Stang., Journal of the American Chemical Society, vol. 113, No. 12, pp. 4571 to 4576, "Preparation and Chemistry of PhI.sup.+ C=CI.sup.30 Ph.2.sup.- OTf, Bis(Phenyl[[(Trifluoromethyl)Sulfonyl]Iodo]Acetylene, A Novel Difunctional Acetylene, Bis(Iodonium) Species and a Stable C.sub.2 -Transfer Agent", 1991.
Rik R. Tykwinski, et al., Journal of Organic Chemistry, vol. 58, No. 19, pp. 5235 to 5237, "A New Synthesis of Alkynyl Sulfones and Single Crystal X-Ray Structure of P-(Tolysulfonyl)Ethyne", 1993.
Rik R. Tykwinski, et al., Tetrahedron, vol. 49, No. 15, pp. 3043 to 3051, "Functionalization of Diynes. Preparation of Bis(Alkynyl) Ditosylate and Dibenzoate Esters and Bis(Alkynyl) Dithiocyanates via Alkynyl Iodonium Chemistry", 1993.
Tsugio Kitamura, et al., "Preparation of (p-Phenylene) bis (aryliodonium) Ditriflates and Their Double Substitution by Some Nucleophiles," Journal of Organic Chemistry, vol. 57, No. 25, (1992), pp. 6810-6814.
Paul M. Gallop, et al., "Highly Effective PQQ Inhibition by Alkynyl and Aryl Mono- and Diiodonium Salts," Journal of Amercian Chemical Society, vol. 115, No. 25, (1993), pp. 11702-11704.
Carl W. Dirk, et al., "Squarylium Dyes: Structural Factors Pertaining to the Negative Third-Order Nonlinear Optical Response," Journal of American Chemical Society, vol. 117, No. 8, (1995), pp. 2214-2225.

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