Organic nickel compounds, production and use thereof as catalyst

Details Organic nickel compounds, production and use thereof as catalyst Organic nickel compounds, production and use thereof as catalyst

1984-09-25

1986-10-28

Sneed, Helen M. S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 21, 556 22, 585502, 585513, C07F 1504

Patent

active

046200215

ABSTRACT:
Olefins such as ethylene can be polymerized with a catalyst which comprises nickel compounds obtained by reacting a nickel-(O) compound or a nickel compound which may be converted in situ into a nickel-(O) compound with an adduct or a mixture of a quinoid compound and a tertiary phosphine and with a compound corresponding to the following general formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.6 -C.sub.12 aryl or C.sub.3 -C.sub.8 cycloalkyl optionally substituted by halogen, hydroxy, C.sub.1 -C.sub.20 alkoxy, nitro or C.sub.6 -C.sub.12 aryloxy; also C.sub.6 -C.sub.12 aryl-C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.12 aryl-C.sub.2 -C.sub.20 alkenyl, C.sub.1 -C.sub.20 alkyl-C.sub.6 -C.sub.12 aryl, C.sub.1 -C.sub.20 alkyl-C.sub.3 -C.sub.8 cycloalkyl and C.sub.6 -C.sub.12 aryl-C.sub.3 -C.sub.8 cycloalkyl, di-C.sub.1 -C.sub.4 alkylamino, optionally substituted phenoxy or alkoxy; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen, silyl, halogen, cyano or R.sup.1 and

REFERENCES:
patent: 4097509 (1978-06-01), Schmidbaur et al.
patent: 4185028 (1980-01-01), Schmidbaur et al.
patent: 4293502 (1981-10-01), Beach et al.
patent: 4529554 (1985-07-01), Beach et al.
patent: 4537982 (1985-08-01), Starzewski et al.
Empsall et al, J. Chem. Soc., Dalton Trans., (15) 1500-1506 (1976).

Affiliated with

Also associated with

Rating

Organic nickel compounds, production and use thereof as catalyst does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Organic nickel compounds, production and use thereof as catalyst, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Organic nickel compounds, production and use thereof as catalyst will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1347604