Stock material or miscellaneous articles – Composite – Of inorganic material
Reexamination Certificate
2000-11-02
2003-02-25
Kelly, Cynthia H. (Department: 1774)
Stock material or miscellaneous articles
Composite
Of inorganic material
C428S212000, C428S917000, C313S502000, C313S506000
Reexamination Certificate
active
06524728
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to an organic electroluminescent device, which is adapted for use as a display device or a light-emitting device such as a spontaneous light flat display, especially an organic electroluminescent color display using an organic thin film as an electroluminescent layer.
In recent years, importance of interfaces between human beings and machines including multimedia-oriented commercial articles is exalted. For more comfortable and more efficient machine operations, it is necessary to retrieve information from an operated machine without failure simply, instantaneously and in an adequate amount. To this end, studies have been made on various types of display devices or displays.
As machines are now miniaturized, there is an increasing demand, day by day, for miniaturization and thinning of display devices. For instance, there is an inconceivable development with respect to the miniaturization of lap top-type information processors of the all-in-one type such as notebook-size personal computers, notebook-size word processors and the like. This, in turn, entails a remarkable technical innovation on liquid crystal displays for use as a display device for the processor.
Nowadays, liquid crystal displays are employed as an interface of a diversity of articles and have wide utility in the fields not only of lap top-type information processors, but also of articles for our daily use including small-sized television sets, watches, desk-top calculators and the like.
These liquid crystal displays have been studied as a key of display devices, which are used as the interface connecting a human being and a machine and cover small-sized to large capacitance display devices while making use of the feature that liquid crystals are low in drive voltage and power consumption. However, liquid crystal displays have the problems that they do not rely on spontaneous light and thus need a greater power consumption for back light drive than for liquid crystal drive, with the result that a service time is shortened when using a built-in battery, thus placing a limitation on their use. Moreover, the liquid crystal display has another problem that it has such a narrow angle of field as not to be suitable for use as a large-sized display device.
Furthermore, the liquid crystal display depends on the manner of display using the orientation of liquid crystal molecules, and this is considered to bring about a serious problem that its contrast changes depending on the angle even within an angle of field.
From the standpoint of drive systems, an active matrix system, which is one of drive systems, has a response speed sufficient to deal with a motion picture. However, since a TFT (thin film transistor) drive circuit is used, a difficulty is involved in making a large screen size owing to the pixel defects, thus being disadvantageous in view of the reduction in cost.
In the liquid crystal display, a simple matrix system, which is another type of drive system, is not only low in cost, but also relatively easy in making a large screen size. However, this system has the problem that its response speed is not enough to deal with a motion picture.
In contrast, a spontaneous light display device is now under study such as on a plasma display device, an inorganic electroluminescent device, an organic electroluminescent device and the like.
The plasma display device employs plasma emission in a low pressure gas for display and is suited for the purposes of a large size and large capacitance, but has the problem on thinning and costs. In addition, an AC bias of high potential is required for its drive, and thus, the display is not suitable as a portable device.
The inorganic electroluminescent device has been put on the market as a green light emission display. Like the plasma display device, an AC bias drive is essential, for which several hundreds of volts are necessary, thus not being of practical use.
In this connection, however, emission of three primaries including red (R), green (G) and blue (B) necessary for color display has been succeeded due to the technical development. Since inorganic materials are used for this purpose, it has been difficult to control emission wavelengths depending on the molecular design or the like. Thus, it is believed that full color display is difficult.
On the other hand, the electroluminescent phenomenon caused by organic compounds has been long studied ever since there was discovered a luminescent or emission phenomenon wherein carriers are injected into the single crystal of anthracene capable of emitting a strong fluorescence in the first part of 1960s. However, such fluorescence is low in brightness and monochronous in nature, and the single crystal is used, so that this emission has been made as a fundamental investigation of carrier injection into organic materials.
However, since Tang et al. of Eastman Kodak have made public an organic thin film electroluminescent device of a built-up structure having an amorphous luminescent layer capable of realizing low voltage drive and high brightness emission in 1987, extensive studies have been made, in various fields, on the emission, stability, rise in brightness, built-up structure, manner of fabrication and the like with respect to the three primaries of R, G and B.
Furthermore, diverse novel materials have been prepared with the aid of the molecular design inherent to an organic material. At present, it starts to conduct extensive studies on applications, to color displays, of organic electroluminescent devices having excellent characteristic features of DC low voltage drive, thinning, and spontaneous light emission and the like.
The organic electroluminescent device (which may be sometimes referred to as organic EL device hereinafter) has a film thickness of 1 &mgr;m or below. When an electric current is charged to the device, the electric energy is converted to a light energy thereby causing luminescence to be emitted in the form of a plane. Thus, the device has an ideal feature for use as a display device of the spontaneous emission type.
FIG. 14
shows an example of a known organic EL device. An organic EL device
10
includes, on a transparent substrate
6
(e.g. a glass substrate), an ITO (indium tin oxide) transparent electrode
5
, a hole transport layer
4
, a luminescent layer
3
, an electron transport layer
2
, and a cathode
1
(e.g. an aluminium electrode) formed in this order, for example, by a vacuum deposition method.
A DC voltage
7
is selectively applied between the transparent electrode
5
serving as an anode and the cathode
1
, so that holes serving as carriers charged from the transparent electrode
5
are moved via the hole transport layer
4
, and electrons charged from the cathode
1
are moved via the electron transport layer
2
, thereby causing the re-combination of the electrons-holes. From the site of the re-combination, light
8
with a given wavelength is emitted and can be observed from the side of the transparent substrate
6
.
The luminescent layer
3
may be made of a light-emitting substance such as, for example, anthracene, naphthalene, phenanthrene, pyrene, chrysene, perylene, butadiene, coumarin, acridine, stilbene and the like. This may be contained in the electron transport layer
2
.
FIG. 15
shows another example of an organic EL device. In an organic EL device
20
, the luminescent layer
3
is omitted and, instead, such a light-emitting substance as mentioned above is contained in the electron transport layer
2
, and thus, the organic EL device
20
is so arranged as to emit light
18
having a given wavelength from an interface between the electron transport layer
2
and the hole transport layer
4
.
FIG. 16
shows an application of the organic EL device. More particularly, a built-up body of the respective organic layers (including the hole transport layer
4
, and the luminescent layer
3
or the electron transport layer
2
) is interposed between the cathode
1
and the anode
5
. These electrodes are, respectively, provided
Asai Nobutoshi
Kijima Yasunori
Shibanuma Tetsuo
Tamura Shinichiro
Garrett Dawn
Kelly Cynthia H.
Sonnenschein Nath & Rosenthal
Sony Corporation
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