Organic electroluminescent device

Details Organic electroluminescent device Organic electroluminescent device

1998-12-09

2001-03-13

Krynski, William (Department: 1774)

Stock material or miscellaneous articles

Composite

Of inorganic material

C313S504000, C313S505000, C313S506000

Reexamination Certificate

active

06200695

ABSTRACT:

This invention relates to an organic electroluminescent (EL) device and more particularly, to an inorganic/organic junction structure suitable for use in a device of the type wherein an electric field is applied to a thin film of an organic compound to emit light.
BACKGROUND OF THE INVENTION
In general, organic EL devices have a basic configuration including a glass substrate, a transparent electrode of tin-doped indium oxide (ITO) etc., a hole transporting layer of an organic amine compound, a light emitting layer of an organic fluorescent material exhibiting electronic conductivity and intense light emission such as an aluminum quinolinol complex (Alq3), and an electrode of a metal having a low work function such as MgAg, wherein the layers are stacked on the substrate in the described order.
The device configurations which have been reported thus far have one or more organic compound layers interposed between a hole injecting electrode and an electron injecting electrode. Structures having two or three organic compound layers are typical.
Included in the two-layer structure are a structure having a hole transporting layer and a light emitting layer formed between the hole injecting electrode and the electron injecting electrode and another structure having a light emitting layer and an electron transporting electrode formed between the hole injecting electrode and the electron injecting electrode. Included in the three-layer structure is a structure having a hole transporting layer, a light emitting layer, and an electron transporting layer formed between the hole injecting electrode and the electron injecting electrode. Also known is a one-layer structure wherein a single layer playing all the roles is formed from a polymer or a mixed system.
FIGS. 3 and 4
illustrate typical configurations of organic EL devices.
In
FIG. 3
, a hole transporting layer
14
and a light emitting layer
15
, both of organic compounds, are formed between a hole injecting electrode
12
and an electron injecting electrode
13
on a substrate
11
. In this configuration, the light emitting layer
15
also serves as an electron transporting layer.
In
FIG. 4
, a hole transporting layer
14
, a light emitting layer
15
, and an electron transporting layer
16
, all of organic compounds, are formed between a hole injecting electrode
12
and an electron injecting electrode
13
on a substrate
11
.
Reliability is a common problem to be solved for these organic EL devices. More particularly, organic EL devices in principle have a hole injecting electrode and an electron injecting electrode and need organic layers for effectively injecting and transporting holes and electrons from the electrodes, respectively. However, the organic materials of which the organic layers are formed are vulnerable during manufacture and have less affinity to the electrodes. Another problem is raised by the significantly accelerated degradation, thermal damages and electric damages of organic thin films as compared with inorganic semiconductor devices such as light emitting diodes (LED) and laser diodes (LD).
Also, most organic materials are relatively expensive. Any partial replacement of constituent films by an inexpensive inorganic material would give an economical merit in the manufacture of cost effective organic EL device-applied products.
There is also a desire to have an organic EL device having a further improved light emission efficiency, a low drive voltage and a minimal current consumption.
To solve this and other problems, a means for taking advantage of both an organic material and an inorganic semiconductor material has been devised. That is, an organic/inorganic semiconductor junction is established by substituting an inorganic p-type semiconductor for the organic hole transporting layer. These efforts are found in Japanese Patent No. 2636341, JP-A 139893/1990, 207488/1990, and 119973/1994. Because of the lack of electron trapping capability, it was impossible to design EL devices which are superior in light emission properties and reliability to prior art organic EL devices.
SUMMARY OF THE INVENTION
An object of the present invention is to provide an organic EL device which can take advantage of both an organic material and an inorganic material, and has heat resistance, an extended effective life, an improved efficiency, a low drive voltage and a low cost.
According to the invention, there is provided an organic electroluminescent (EL) device comprising a hole injecting electrode, an electron injecting electrode, at least one organic layer between the electrodes, and an inorganic insulating hole injecting layer between the hole injecting electrode and the at least one organic layer. The inorganic insulating hole injecting layer consists essentially of silicon oxide or germanium oxide or a mixture of silicon oxide and germanium oxide, and has an average composition represented by the formula: (Si
1-x
Ge
x
)O
y
wherein x is from 0 to 1 and y is from 1.7 to 1.99, as analyzed by Rutherford back-scattering. Preferably, in the formula, x is from 0 to 1 and y is from 1.85 to 1.98.
Also preferably, the inorganic insulating hole injecting layer has a thickness of 0.05 to 10 nm, more preferably 0.1 to 5 nm, and most preferably 0.5 to 3 nm.


REFERENCES:
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patent: 5969474 (1999-10-01), Arai
patent: 5981092 (1999-11-01), Arai et al.
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patent: 5-3080 (1993-01-01), None
patent: 8-288069 (1996-11-01), None
patent: WO 97 42666 (1997-11-01), None
Patent Abstracts of Japan; vol. 1998, No. 02, Jan. 30, 1998 & JP 09 260062, Oct. 3, 1997 & U.S. 5,981,092 Nov. 9, 1999.

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