Organic compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260180, C07C14356

Patent

active

039364968

ABSTRACT:
The invention concerns a novel process for the production of benzidine compounds having at least one nuclear sulphonic acid group, comprising reacting a nitro- or nitroso-benzene with an aniline or mono-N-alkyl aniline, reducing the reaction product to a hydrazo compound and rearranging this to the benzidine compound.

REFERENCES:
patent: 2765301 (1956-10-01), Cashion
Roberts et al., "Basic Principles of Organic Chem.," pp. 869-871, (1965).
Sandler et al., Organic Functional Preparations, Vol. 12, pp. 347-348, (1968).
Bloink et al., Journal Chemical Society, pp. 950-954, (1950).
Martynoff, Bull. Soc. Chim., France, (1951), 214.
Martynoff, Compt. Rend., 223, 747, (1946).
Baeyer, Ber., 1, 1638, (1874).
Bates, "The Synthesis of Benzene Derivatives," pp. 62-63, 108-111, D. Van Nostrand Co., N.Y., 1926.
Roberts et al., "Basic Principles of Organic Chemistry," W. A. Benjamin, Inc., New York, pp. 869-871, (1965).

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