Organic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 7, 556 13, 556 14, 556 16, 556 30, 4274343, 4284111, 428688, 428690, 428704, C07F 915, C07F 1500

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active

049819844

ABSTRACT:
Langmuir Blodgett films are provided having second order molecular hyperpolarizability of at least 30.10.sup.-50 C.sup.3 m.sup.3 J.sup.-2. combined with chemical stability and a melting point of over 70.degree..
They also have desirable pyroelectric properties shown by a static pyroelectric coefficient of at least 0.0039 nCcm.sup.2 k.sup.-1. The films comprise compounds of the following formula: ##STR1## wherein M is ruthenium, iron or cobalt; R.sup.1 is cyclopentadienyl, methylcyclopentadienyl, pentamethylcyclopentadienyl or indenyl;

REFERENCES:
"On the History of Langmuir-Blodgett Films", by G. Gaines, Jr. Thin Solid Films 99 (1983), pp. 4-8.
1986 Proc. Int. Symp. on the Applications of Ferroelectric Materials, Philadelphia, by D. Neal et al.
J. Chem. Soc. (1), 1971, 2376, by T. Blackmore et al.

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