Organic carrier supported metallocene catalyst for olefin polyme

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502150, 502154, 502156, 502158, 502159, 556 11, 556 52, 556 53, 526127, 526160, 526904, 526943, C08F 4649

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active

056101155

ABSTRACT:
The organic carrier supported metallocene catalyst of the present invention is prepared by preparing a ligand complex of a silicone compound having at least one halogen, an alkyl group and a cycloalkane dienyl group, activating styrene polymer or styrene/divinylbenzene copolymer with a strong base including a metal atom such as Li, Na, K or Mg, reacting the activated polymer or copolymer with the ligand complex of a silicone compound so that the ligand may be supported on the activated polymer or copolymer, and reacting the organic carrier supported ligand with a compound of a transition metal of Group IVb of the Periodic Table or Lanthanides of Atomic Number 58-71. The styrene polymer or styrene/divinylbenzene copolymer may be alkylated by Friedel-Crafts alkylation before they are activated with a strong base.

REFERENCES:
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patent: 4921825 (1990-05-01), Kioka et al.
patent: 5122491 (1992-06-01), Kioka et al.
patent: 5346925 (1994-09-01), Sugano et al.
patent: 5362824 (1994-11-01), Furtek et al.

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