Optically active rhodium complexes of 3,4-bis(diarylphosphino)py

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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548412, C07F 965, C07F 930

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active

049239961

ABSTRACT:
The invention relates to rhodium complexes of the formula

REFERENCES:
patent: 4168963 (1979-09-01), Rupp et al.
patent: 4634775 (1987-01-01), Beck et al.
Nagel et al., "Synthese N-Substituierter (R,R)-3,4-Bis(Diphenylphosphino)-Pyrrolidine und Anwendung Ihrer Rhodiumkomplexe zur Asymmetrischen Hydrierung von .alpha.-(Acylamino Acrylsaure-Derivaten", Chem. Ber., 119 (1986), pp. 3326 to 3343.
"Conformational Analysis in Multisulfur Heterocycles. VI. 3,3:6,6-Bis(Pentamethylene-S-Tetrathiane. Slow Pseudorotation in the Twist Conformer of a 6 Ring", Journal of the American Chemical Society, 93:12, Jun. 16, 1971, pp. 3058-3060.

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