Optically active N-.alpha.-fluoroacryloylamino acid derivatives

Details Optically active N-.alpha.-fluoroacryloylamino acid derivatives Optically active N-.alpha.-fluoroacryloylamino acid derivatives

1992-10-01

1994-10-11

Rizzo, Nicholas S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560 39, 560 40, 560 43, 560156, C07C22930

Patent

active

053548841

ABSTRACT:
.alpha.-Fluoro-substituted N-acryloylamino acid derivatives of the formula ##STR1## are used to make polymers optionally for chromatographic resolution of racemates into their enantiomers. The fluorine atom improves performance in many instances.

REFERENCES:
patent: 3452182 (1969-06-01), Haas
patent: 4101672 (1978-07-01), Hubele et al.
patent: 4474692 (1984-10-01), Oka et al.
Undheim, Chemical Abs. #72 (3) 11894g, 1969.
Chromatographic Science Series Bd. 40, 1988, New York; Basel; Seiten 179-198; Blaschke "Substituted Polyacrylamides as Chiral Phases for the Resolution of Drugs".

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