Optically active dimethylorganoboranes

Details Optically active dimethylorganoboranes Optically active dimethylorganoboranes

1990-03-26

1993-05-11

Robinson, Allen J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Boron containing

564 8, 564 9, 564307, 564395, 564445, 564460, 564462, 564463, 564469, 564485, 564509, 564302, 568 1, C07C 902, C07C20900

Patent

active

052103102

ABSTRACT:
A novel process for producing hindered and unhindered primary amines represented by the formula RNH.sub.2 and R*NH.sub.2 in high yields from novel intermediates RBMe.sub.2 or R*BMe.sub.2 wherein R is an organo group, R* is a chiral organo group, attached to boron, B is boron and Me is methyl.

REFERENCES:
Brown et al. "Organoborans for Synthesis" Titrohedron vol. 43, No. 18, pp. 4071-4078, 1987.

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