Optically active derivatives of gycidol

Details Optically active derivatives of gycidol Optically active derivatives of gycidol

1992-07-21

1994-07-26

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549556, C07D30334

Patent

active

053328434

ABSTRACT:
Optically active derivatives of glycidol are disclosed. These novel compounds, (2S) and (2R) glycidyl m-nitrobenzenesulfonate and (2S) and (2R) glycidyl p-chlorobenzenesulfonate can be readily crystallized to high enantiomeric purity. Their use in other synthesis reactions is also described.

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McClure et al., Journal of the American Chemical Society, 101:13 pp. 3666-3668 (Jun. 20, 1979).
Metzger, Mosaic, 16:1, Jan./Feb. 1985, pp. 34-41.
Sharpless, K. B., Chem. in Britain, 22:1 (Jan. 1986) pp. 38-40, 43-44.

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