Optically active derivatives of glycidol

Details Optically active derivatives of glycidol Optically active derivatives of glycidol

1993-01-15

1994-09-06

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30334

Patent

active

053449479

ABSTRACT:
Optically active derivatives of glycidol are disclosed. These compounds, (2S) and (2R) glycidyl tosylate and (2S) and (2R) glycidyl 4-chloro-3-nitrobenzenesulfonate can be readily crystallized to high enantiomeric purity. Their use in other synthesis reactions is also described.

REFERENCES:
patent: 4471130 (1984-09-01), Katsuki et al.
patent: 5153338 (1992-10-01), Sharpless et al.
Aldrich Chemical Co, "Chiral Building Blocks," J. Org. Chem., 50(25), (1985).
N. Nakabayshi et al., Bull Chem Soc. Jap. "Some reactions of the glycidyl esters of sulfonic acid" 39, 413-417 (1966).

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