Optically active cobalt (II) complexes and method for the prepar

Details Optically active cobalt (II) complexes and method for the prepar Optically active cobalt (II) complexes and method for the prepar

1996-09-27

1998-05-26

Nazario-Gonzalez, Porfirio

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 42, 556 45, 556 51, 556130, 556136, 556146, 568880, 568885, C07F 1506, C07F 700, C07C 2914

Patent

active

057567905

ABSTRACT:
The invention provides a method for preparing an optically active alcohol comprising the step of reacting a ketone compound with a hydride reagent in the presence of an optically active metal compound. The resulting optically active alcohols are useful as intermediates for the synthesis of physiologically active compounds such as drugs and pesticides, functional materials such as liquid crystals, and raw materials for synthesis in fine chemistry. A novel optically active cobalt (II) complex useful as a catalyst is also provided.

REFERENCES:
Massonneau et al., Journal Of Organometallic Chemistry, vol. 288, pp. C59-C60 (1985).

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