Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Patent
1986-12-24
1990-10-30
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
556134, 556148, 558252, 560 39, 562 26, 562444, C07F 108, C07F 306, C07F 1502, C07C32700
Patent
active
049669850
ABSTRACT:
A carboalkylated amino alcohol having each of the below shown formulae is novel and optically active. A separating agent comprising the alcohol and a support is effectively useful to separate a variety of racemates for example with chromatography. The alcohol may be chemically or physically combined with the support. ##STR1## [wherein Ph represents a phenyl group, R represents a hydrogen atom, an alkyl group having the carbon number of 1 to 10, or an aryl group having the carbon number of 6 to 10, X represents an --0-- group or a --S-- group, and Z represents a hydrogen atom, an alkyl group having the carbon number of 1 to 10 or a metal element].
REFERENCES:
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patent: 4529713 (1985-07-01), Jouquey et al.
patent: 4532342 (1985-07-01), Hoefle et al.
patent: 4619984 (1986-10-01), Yuki et al.
Chemisches Zentralblatt, vol. 140, No. 23, Jun. 4, 1969, pp. 127-128, Berlin K. Jankowski et al., Reaktionen von Epoxiden mit Glycin und seinen Derivaten, Canadian Journal of Chemistry, 1967, vol. 45(23), pp. 2865-2877.
Journal of the American Chemical Society, vol. 108, No. 5, pp. 1103-1104, P. J. Sinclair et al., "Electrophilic Glycinates: New and Versatile Templates for Asymmetric Amino Acid Synthesis".
Hasegawa Masaki
Saigo Kazuhiko
Tachibana Kouzou
Yuki Yoichi
Daicel Chemical Industries Ltd.
Shaver Paul F.
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