Optically active 3-(2-trifluoro-1-hydroxyethyl)propenyl benzyl e

Chemistry: molecular biology and microbiology – Process of utilizing an enzyme or micro-organism to destroy... – Resolution of optical isomers or purification of organic...

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435156, C12P 722

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active

050473468

ABSTRACT:
3-(2-Trifluoro-1-hydroxyethyl)propenyl benzyl ether or derivatives thereof having the formula ##STR1## wherin R is a substituted or not substituted phenyl group and a mark * shows an asymmetric carbon atom, and derivatives thereof are provided, which are useful as a material for preparing liquid crystal compound.

REFERENCES:
Chemical and Pharmaceutical Bulletin, vol. 35 (4, 1633-1636, 1987).
Phosphorus and Sulfur, 1986, Col. 27, pp. 371-374.
Tetrahedron Letters, vol. 25, No. 37, pp. 4117-4120 (1984) and Communications Jun./Jul. 1985, pp. 659-663.
Twelfth (12th) Fluorine Chemistry Forum, Joint Auspices Organic Synthesis Chemistry Society/Japan Chemistry Society, "Asymmetric Hydrolysis of CF.sub.3 -Containing Compound Having C--C Multibond and its Application," Yamazaki, T., H. Iwatsubo and T. Kitazume, Oct. 1987.

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