Optical recording medium and optical memory device

Dynamic information storage or retrieval – Storage medium structure – Optical track structure

Reexamination Certificate

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C428S064400, C430S270130

Reexamination Certificate

active

06411591

ABSTRACT:

TECHNICAL FIELD
The present invention relates to an optical recording medium and an optical memory device capable of reading or recording in real time digital information, such as computer data, facsimile signals and digital audio signals, by an optical beam such as a laser beam. More specifically, the invention relates to a high density phase change optical disk and a high density read-only optical disk.
BACKGROUND ART
As information diversification has progressed in recent years, there are growing demands for a rewritable optical disk that allows a user to record or rewrite information. Further, an increase in the amount of information has called for large-capacity rewritable optical disks. Under these circumstances, a variety of research organizations are actively engaged in studies for increasing the recording density of an optical disk. These studies include those on a method for reducing the size of a recording mark reducing the apparent spot diameter of an information reading laser beam by reducing the wavelength of a recording laser beam or by increasing the numerical aperture (NA) of a focusing lens to increase the recording density, as described in the Nikkei Electronics, Vol. 521, page 92 (1991). A super-resolution reading method using a super-resolution layer of organic pigments is reported in the proceedings of lectures in the Japan Society of Applied Physics, page 1000, 19p-K-5 (autumn, 1994).
The method of increasing the recording density by using the super-resolution layer to reduce the apparent spot diameter of an information reading laser beam is important because it can easily be combined with other recording density enhancing methods.
DISCLOSURE OF INVENTION
The object of the invention is to provide an optical recording medium and an optical memory device which have a large capacity and can perform a recording or reading operation a large number of times.
In the present invention, the recording medium has a construction in which a super-resolution layer (hereinafter called a mask layer) whose refractive index is changed in a part of a light spot by a laser beam of 2 to 4 mW is sandwiched by inorganic protective layers and in which the difference in the amount of reflected light between a crystalline state of the film and an amorphous state of the film is so small in either the region where the refractive index has changed or other remaining regions that the playback signals are difficult to identify.
That is,
(1) An optical recording medium that enables at least information to be read out by irradiation of a light, comprises: a mask layer containing at least one of elements in groups Ib, IIb, IIIa to VIIa, and VIII in 10 to 40 atomic percent and also containing oxygen; wherein when the read operation is performed at a reading laser power of 1 mW by using a lens with a predetermined wavelength and a predetermined numerical aperture and with a light spot focused to nearly a diffraction limit, the difference between the amount of reflected light from recording marks and the amount of reflected light from spaces between the recording marks is 25 or less, with the amount of reflected light from the spaces taken as 100, and there is a laser power in a reading laser power range of 2 to 4 mW that causes the difference between the amount of reflected light from recording marks and the amount of reflected light from spaces between the recording marks to be 30 or more, with the amount of reflected light from the spaces taken as 100. Alternatively,
(2) An optical recording medium that enables at least information to be read out by irradiation of a light, comprises: a mask layer containing at least one of elements in groups Ib, IIb, IIIa to VIIa, and VIII in 10 to 40 atomic percent and also containing oxygen; wherein when the read operation is performed by using a lens with a predetermined wavelength and a predetermined numerical aperture and with a light spot focused to nearly a diffraction limit, there is a laser power in a reading laser power range of 2 to 4 mW that causes the difference between the amount of reflected light from recording marks and the amount of reflected light from spaces between the recording marks to be 25 or less, with the amount of reflected light from the spaces taken as 100, and in a lower laser power range there is a laser power that causes the difference between the amount of reflected light from recording marks and the amount of reflected light from spaces between the recording marks to be 30 or more, with the amount of reflected light from the spaces taken as 100. More preferably, the mask layer further includes silicon.
The measurement of the reflected light is taken at the recording marks and spaces that are three times or more longer than the shortest recording mark.
More preferably, the mask layer uses an inorganic film containing at least one of elements, such as Co, O and Si, in 30 atomic percent or more to equivalently reduce the spot diameter of the laser beam. The conventional organic super-resolution layer has a property such that, when applied with a laser beam with an intensity in excess of a threshold value for a predetermined duration, the layer loses molecules in a ground state and thus can no longer absorb light (saturation of absorption). On the other hand, the mask layer of this invention has a property such that when the mask layer is applied with a laser beam, the refractive index changes without changing the absorption coefficient. To take full advantage of this property, a laminated film is provided with the characteristics described in (1) and (2) above. As a result, in a recording medium of the type (1), when the normal reading laser power of about 1 mW is used, the difference in the amount of reflected light between the crystalline state and the amorphous state of the phase change recording film is small and therefore the reproduced signal small. As the reading laser power is increased, the refractive index of the mask layer changes in a part of the light spot to produce a large playback signal. It should be noted, however, that even at this time the remaining region in the light spot has a small difference in the amount of reflected light or, in other words, masked. When the reading laser power is at around 1 mW, the amounts of reflected light from both states may be low. However, it is not required that the reflected light amounts from both states be low. As described above, when information on the track is read out, only the information on those portions where the refractive index is changed can be read. This produces the same effect as when the information is read by using a small light spot (super-resolution effect). At this time, if the mask layer is provided between the substrate with at least its surface formed of an organic material and the recording film, the super-resolution effect can be obtained at a low reading laser power. However, because the mask layer absorbs light, the recording power becomes high. In that case, it is preferred that the mask layer be sandwiched between other inorganic protective layers to avoid unwanted influences from substrate deformations caused by heat generated in the mask layer. In another structure, the mask layer may, for example, be formed between an aluminum alloy reflective layer and a ZnS-based inorganic protective layer, which is on the reflective layer side of the recording film. The mask layer, when interposed between inorganic protective layers, has an increased mechanical strength and thus undergoes a minimal deformation even after a large number of rewriting operations. When the mask layer is formed on the reflective layer side of the recording film, the heat generated in the mask layer can be released toward the reflective layer, minimizing thermal damages to the mask layer. This reduces deformations and structural breaks of the layer due to heat during the recording operation. At this time, a reflective layer with a large thermal conductivity should preferably be used because it helps release heat more quickly. It is more preferred that the mask layer be for

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