Optical data storage materials for blue-light DVD-R

Details Optical data storage materials for blue-light DVD-R Optical data storage materials for blue-light DVD-R

1999-05-19

2001-04-10

Evans, Elizabeth (Department: 1774)

Stock material or miscellaneous articles

Circular sheet or circular blank

C428S064200, C428S064400, C428S064800, C428S913000, C430S270140, C430S270160, C430S495100, C430S945000, C369S283000, C369S288000

Reexamination Certificate

active

06214431

ABSTRACT:

TECHNICAL FIELD
This invention relates to a category of photochromatic materials suitable for blue-light and red-light rewritable digital video discs (DVD) for information storage, and the discs using these materials.
DESCRIPTION OF THE PRIOR ART
The digital video disc (or digital versatile disc, DVD) debuted at November, 1996, has caught the global attention, and hence been honored as “The Memory of 21st Century.” This is because, as comparing to all different kinds of optical discs, DVD has much greater storage density with complete digitalization. It breaks a new era for TV, audio, communication, computer and data storage. Following the currently negotiated international standard, DVD should use substrates with the same size of a compact disc (CD), i.e. 120 mm in diameter. DVD can be recorded on both sides, having a storage capacity of 4.7 Gb per side, which is 7 times greater than that of a CD with the same storage area (the capacity of which is 650 Mb). Because of the high capacity, the video playing time can be 133 min, which can hold a full-length movie. Besides, the expected value of resolution of DVD is 800 lines which is much better than the conventional TV. The Dolby Surround AC-3 can be used for sound system, and a recorded movie may have 8 different dialogue languages and up to 32 different captions, if necessary.
It is recognized internationally that, increasing the storage density (storage capacity per unit area) is still the direction for further development of DVD. It is known that the storage density of an optical disc is intimately related to the spot size of the laser beam used. Because the diameter of the laser spot is directly proportional to the wavelength of the light, therefore, to decrease the spot size, shorter wavelength should be used. Formerly, CD and video compact discs (VCD) use an infra-red laser beam with wavelength of 780 nm, and recently, DVD would use a red beam with wavelength 650 &mgr;m comes from a semiconductor laser, the spot diameter of which is about 1 mm. If DVD can use blue light with a wavelength of 450 nm, then the storage capacity of a single side can be increased from 4.7 Gb to about 10 Gb. For a motion picture, a double-sided blue-light DVD can record 2 full-length movies with a resolution corresponding to a high-definition television (HDTV), and obviously this cannot be done by a red-light DVD. Therefore, to increase the storage density of a DVD, the most possible and acceptable way is using a solid laser that emits blue-light, and hence the “blue-light DVD” is termed as “DVD of the next generation”.
A conventional DVD disc is a read-only memory (ROM). Just like the earliest CD, the information storage is realized by forming mechanical cavities on the disc surface. Therefore, no problem will be raised for the storage media. For a write-once memory, or DVD-R, many people entrust their hope for the magneto-optical (MO) or phase-transition (PT) materials as originally prepared for writable CD. MO material is an alloy formed of a rare-earth and a transition metal. This alloy has an axis of magnetization perpendicular to the surface of storage film. Using a laser to demagnetize and an external magnetic field to determine the directions of magnetization, positive or negative, “0” and “1” can be distinguished. The PT material is usually a multi-element amorphous semiconductor, e.g. In
3
SbTe
2
, which can have structural transformation between non-crystalline and crystalline states under the effect of laser pulses with different energies. More specially, using a laser beam to illuminate the surface of this film and changing the beam power and pulse width, the effective spot can change its structure from non-crystalline state to crystalline, or vice versa. There are significant differences between the reflectivity of these two states, therefore, they can be used as “0” and “1” to write-in or read-out the information. These two materials have entered the market gradually, however, they have some drawbacks. For instance, the MO materials require an “erase procedure” before “write-in”, i.e. they cannot be used for “direct overwriting”. Hence the “write-in” time should be longer, and most likely to be discarded in the near future. PT materials require a relatively complicated technology, and higher cost. The third category is the so-called photochromatic material (PK), the spectral characteristic curve of which will be changed after a certain amount of laser irradiation. It provides good contrast from transmissivity before and after the activation of light. The working principle is rather simple, its driver has less parts, and the cost of material is relatively low. Especially it is hopefully that the “photon hole-burning” method can be used for further increment of the capacity which, in principle, neither MO nor PT can have the same advantage. However, since there are some difficulties, PK materials in the past have only been investigated by few institutions and have not been commercialized.
SUMMARY OF THE INVENTION
The purpose of the present invention is to provide an optical information storage material which is suitable for blue-light DVD-R as well as red-light DVD-R.
Another purpose of this invention is to provide a kind of compact disc which employs the material mentioned above.
To realize these purposes, this invention provides a category of photochromatic material, the nonstoichiometric metal-organic complex Ag
1−&bgr;
(TCNQ), to meet the requirements of optical information storage for both blue-light and red-light DVD-R, wherein, Ag is silver; TCNQ is tetracyano-p-quinodimethane C
12
H
4
N
4
, &bgr; is an optional parameter chosen by different specifications. Generally, &bgr;<0.4, and 0.1<&bgr;<0.2 is preferred.
The basic structure of optical disc made of the above-mentioned material includes a substrate, a thin film of the storage material on the substrate, and a thin gold film on the top of the film.
Metal-organic complex Ag
1−&bgr;
(TCNQ) has stable characteristics. They can present charge transfer during the incidence of photons and thus lead to change optical performances. Furthermore, this material has its excellent behavior at the color axis of blue light, i.e. wavelength =450 nm. Specifically, the transmissivity of the material varies greatly before and after the “write-in” process of the blue-light laser. Therefore, good signal-to-noise ratio will be available for this kind of discs.
Inspected by Raman spectra, the change in color (spectrum) induced by light is proved to be derived from the change of molecular states. Theoretically, the process of the transition is very fast. Preliminary tests show that the transition time is about 20~30 ns. Therefore, the speed for writing is very quick under enough power of light. This is also a necessary condition for such a large-scale memory as DVD-R.
Since the solid laser that emits blue light is still in the phase of research, no corporation in the market have declared that they can fabricate the blue-light DVD-R. Yet for an industrial institution, the best way for the future development is to be compatible with the current products, in other words, it is mostly preferred if a design has downward compatibility. It is known that the threshold power of writing of a metal-organic complex is almost independent on the wavelength of incidence light. In other words, if the requirement of spot size is satisfied, in principle, any kind of laser can be used. Fortunately our thin film material has another region of large contrast just at the wavelength 650 nm (red). Therefore, our material can be used for red-light DVD-R, with a laser device similar to that used in a conventional DVD driver, and when the blue-light laser is commercially available, blue-light DVD-R can be manufactured immediately using the same material.
It is also worthwhile to notice that, actually the DVD-R made from this material is not write “once” but more. Experiments show that its number of “write-erase” cycles can be more than 20. Therefore, in the future, this kind of DVD-R will probab

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