Optical coating having low refractive index

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S208000, C526S303100, C526S320000, C526S321000, C526S333000

Reexamination Certificate

active

06686431

ABSTRACT:

FIELD OF THE INVENTION
The present invention is directed to transparent and low refractive index optical coatings for use in light transmitting electronic devices. In particular, the present invention is directed to low refractive index optical coatings manufactured from hydrogels.
BACKGROUND OF THE INVENTION
By definition, a hydrogel is a polymeric material which exhibits the ability to swell in water and retain a significant fraction, (e.g., greater than 20%) of water within its structure, but which will not dissolve in water. The hydrogel forms an equilibrium state with water, and maintains its equilibrium shape. Included in this definition are a wide variety of natural materials of both plant and animal origin, materials prepared by modifying naturally occurring structures, and synthetic polymeric materials.
Synthetic hydrogels include polyacrylic acid, polyvinyl pyrrolidone, polyvinyl alcohol, polyacrylamide, polyhydroxybutyl acrylate and methacrylate, polyhydroxyethyl acrylate and methacrylate, polyethylene oxide and polyurethane. Hydrogels with various equilibrium content of water are known and used for manufacturing soft contact lenses and for medical applications such as wound dressings and adhesives for biomedical electrodes.
U.S. Pat. No. 2,976,576 describes the use of poly 2-hydroxyethyl methacrylate resin for contact lenses and body implants.
U.S. Pat. No. 3,419,006 describes the use of crosslinked poly(ethylene oxide) gels for wound dressings.
U.S. Pat. No. 3,963,685 describes the preparation of methanol soluble poly 2-hydroxyethyl methacrylate for wound care dressings using high purity 2-hydroxyethyl methacrylate monomer having not over 0.035 weight percent of alkylene glycol dimethacrylate impurities.
U.S. Pat. No. 3,963,805 describes a process for producing water swellable polyalkylene oxide wherein a mixture of polyethylene oxide and acrylic acid in a hydrocarbon solvent is heated.
U.S. Pat. No. 4,258,715 describes the use of a radiation crosslinked acrylamide polymer composition for sealing ostomy appliances.
GB 2196973 describes a hydrophilic copolymer useful for contact lenses and medical purposes. The hydrophilic copolymer is prepared by the copolymerization of a monomer mixture of 2-hydroxyethyl methacrylate and 2-(2-hydroxyethoxy)ethyl methacrylate with the free methacrylic acid or acrylic acid or their sodium, potassium and ammonium salts in the presence of radical initiators, and a crosslinking agent having at least two olefinic double bonds.
U.S. Pat. No. 5,115,801 describes a hydrogel burn dressing product in which the hydrogel material comprises from about 15% to about 30% by weight of a polyhedric alcohol, from about 8% to about 14% by weight of an isophorone diisocyanate terminated prepolymer, from about 5% to about 10% by weight of a polyethylene oxide based diamine, up to about 1% by weight of a salt, and the balance water.
WO 00/14131 describes a photopolymerizable composition useful in the production of wound dressings, electrodes for application to human or animal bodies or transdermal patches. The composition comprises a first monomer having olefinic unsaturation and a flexible hydrophilic chain, a second monomer having olefinic unsaturation and high polymerization efficiency and which can contribute to tackiness on curing, a crosslinking agent and a photoinitiator.
The present invention is directed to providing a transparent optical coating having a refractive index of less than about 1.40. The present invention is further directed to a method of providing a hydrogel coating having a refractive index of less than about 1.40 and an equilibrium water content of at least 50%.
SUMMARY OF THE INVENTION
A transparent optical coating is provided which comprises a hydrogel having a refractive index of less than 1.40 and an equilibrium water content of at least about 50 wt. %. A method for producing the optical coating is further provided whereby the hydrogel is made by the process comprising polymerizing in water, (a) a first oligomer of the formula
wherein R
1
is a hydroxyl or C
1
-C
4
alkoxy; R
2
is a C
2
-C
4
alkoxy; R
3
is —O— or —CO—; R
4
, R
5
and R
6
are independently hydrogen, or C
1
-C
4
alkyl; and n is 1-25; with (b) a second oligomer of the formula
wherein R
8
is H or CH
3
and R
7
is a polar linking group and is water soluble; and initiating polymerization by irradiation or a free radical initiator.
An electronic device is also provided which comprises (a) two light transmitting substrates, each substrate having an inner surface; and (b) a transparent hydrogel coating positioned between said two substrates and conforming to the inner surface of each substrate; wherein the hydrogel coating has a refractive index of less than 1.4.
DETAILED DESCRIPTION OF THE INVENTION
The hydrogel coatings of the present invention are generally obtained by polymerizing hydrophilic, water soluble oligomers in the presence of water. The equilibrium content of water for the hydrogels of the present invention is at least about 50 wt. %. In one embodiment, the equilibrium content of water of the hydrogel is at least about 75 wt. %. In another embodiment, the equilibrium content of water of the hydrogel is at least about 80 wt. %. In yet another embodiment, the equilibrium content of water of the hydrogel is at least about 90 wt. %. The refractive index for the hydrogel coatings of the present invention is less than about 1.4. In one embodiment, the refractive index is less than about 1.35.
The hydrogel coatings of the present invention can be used in light transmitting electronic devices, for example in the screens for computer monitors, computer laptops, televisions, cellular phones and video displays. The hydrogel coating is positioned between two light transmitting substrates and conforms to the inner surface of each substrate. The inner surface of each substrate may be smooth or may be textured or irregular.
The hydrogels can be formed by polymerization of a large variety of water soluble monomers in the presence of difunctional crosslinking agents by free radical polymerization and by crosslinking of water-soluble oligomers in the presence of difunctional crosslinking agents by free radical polymerization or step-reaction polymerization. Crosslinking of previously formed water soluble polymers can also be effected by complexation with difunctional species, such as difunctional organic reactants or by exposure to ionizing radiation such as gamma rays or electron beam radiation. Many naturally occurring polymers such as gelatin can be reversibly and non-covalently crosslinked by manipulating gelation temperatures.
Examples of water-soluble monomers subject to free radical polymerization for use as a hydrogel are acrylic acid, hydroxyethyl methacrylate, acrylamide, methacrylamide, and vinyl pyrrolidone. Diacrylate esters of polyethylene oxide are typical free radical crosslinking agents used in these compositions. Examples of water-soluble oligomers subject to free radical polymerization for use as hydrogels are methoxypolyethyleneglycol acrylate or polyethyleneglycol methacrylate with polyethyleneglycol diacrylate as the crosslinking agent by redox, ultraviolet radiation or ionizing radiation. An example of water-soluble oligomers subject to step-reaction polymerization is a mixture of polyethyleneglycol and polyethyleneglycol based diamine with diisocyanate terminated prepolymer as the crosslinking agent. Examples of hydrogel formation by the crosslinking of water-soluble polymers are the crosslinking of polyvinylpyrrolidone, polyvinyl alcohol, polyacrylamide and polyethylene oxide by ionizing radiation. Examples of naturally occurring polymers which form gels by thermal gelation are gelatin and karaya gum.
In one embodiment of the present invention, the hydrogel is made of a polymer formed by polymerizing in water a soluble long chain oligomer having one olefinic group and a long chain oligomer having two olefinic groups. The first oligomer is a polyoxyalkylene chain connected to an ethylene or other alkylene group. This oligomer is of the f

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