Optical article containing a linear polymer exhibiting a high le

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528373, 350356, G02B 600, G02F 103, C08G 6362

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active

049001272

ABSTRACT:
An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of a linear polymer containing as pendant groups polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer contains repeating units derived from vinyl addition polymerization, at least 5 percent of the repeating units incorporate the molecular dipoles as pendant groups, and the molecular dipoles include a sulfonyl electron acceptor moiety.

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