Optical article containing a linear condensation polymer exhibit

Compositions – Light transmission modifying compositions

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252589, 385141, 385 8, F21V 900, F21V 904, G02B 600, G02B 610

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050750437

ABSTRACT:
An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of a linear polymer containing polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer is a condensation polymer including in its backbone a plurality of molecular dipoles including sulfonyl electron acceptor moieties sequentially arranged to reinforce electron displacement along the polymer backbone.

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