Ophthalmic lenses with heterocyclic chromene compounds

Optics: eye examining – vision testing and correcting – Spectacles and eyeglasses – Ophthalmic lenses or blanks

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252586, G02C 710

Patent

active

056317204

ABSTRACT:
The invention relates to ophthalmic lenses comprising a transparent organic polymer material and photochromic compounds of general formula ##STR1## wherein R.sup.a, R.sup.b and R.sup.c are hydrogen; alkyl; aryl; OR, SR, COR or COOR, where R denotes hydrogen, alkyl or aryl, amino of formula NR.sub.1 R.sub.2 where R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl or an aryl; a halogen atom; a mono- or polyhaloalkyl group; or an NO.sub.2, CN or SCN group; n and m denote integers from 1 to 5; p is equal to 1 or 2; and H is an aromatic heterocycle having the general formula: ##STR2## wherein: X, Y and Z represent independently of each other, a CR.sub.8 radical or a nitrogen atom, and one or two of X, Y and Z is a nitrogen atom and R.sub.8 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl and phenyl; and R.sub.4 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl and phenyl.

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Azerad, "No. 490.-Isomerisation acide des tocoquinones. II. - Synthese de dichromannes apparentes aux tocoquinones," Bulletin de la Societe Chimique de France, 8:2728-2735, 1967, published in Europe (Month Unavailable).
Okazaki et al., "Preparation of Chromene Compounds as photochromic Substances," Chemical Abstracts, 115(19):1021, Abstract No. 207975k (No Date).
Tanaka et al., "Naphthopyrans and Analogs as Photochromic Agents and their Preparation," Chemical Abstracts, 113(9):Abstract No. 78167f, 1990, published in U.S.A. (Month Unavailable).

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