Operation of staged adsorbent membranes

Gas separation: processes – Selective diffusion of gases – Selective diffusion of gases through substantially solid...

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95 47, 95 49, 95 50, 95 51, 95 96, 95115, B01D 5322, B01D 53047

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057530114

ABSTRACT:
A staged adsorbent membrane system is operated to separate a gas mixture wherein more strongly adsorbed secondary components preferentially adsorb and permeate through the adsorbent membrane in the first stage. Less strongly adsorbed primary components are recovered therefrom in a nonpermeate gas product stream. Preferably two stages are utilized wherein the permeate gas from the first stage is introduced into the second stage and the nonpermeate gas from the second stage is recycled to the first stage as additional feed gas to increase the overall recovery and/or purity of the nonpermeate gas product. The two-stage membrane system is operated such that the ratio of the recovery of the primary component in the first stage to the recovery of the primary component in the second stage is less than about 1.0. The method is particularly useful for the recovery of hydrogen from hydrogen-containing gas mixtures.

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