Open-pentadienyl metallocenen ligands, polymerization catalysts/

Organic compounds -- part of the class 532-570 series – Organic compounds – Rare earth containing

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502102, 502103, 502117, 502152, 502155, 502158, 556 11, 556 22, 556 23, 556 32, 556 43, 556 52, 556 53, C07F 500, C07F 900, C07F 1700, C07F 700

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060692375

ABSTRACT:
New metallocene ligand systems and catalysts/catalyst precursors are described where the ligand system contains at least one open-pentadienyl ligand characterized by an acyclic six .pi. electron delocalized, five atomic center structure. The open pentadienyl ligand is bonded to either another pentadienyl ligand or a Cp ligand by a bridging group. The metal is from group 3-5 or the Lanthanides. These metallocene catalysts/catalyst precursors optionally in combination with co-catalysts can be used to generate a wide variety of different polymer types including HDPE, LLDPE, LHDPE, ethylene/propylene elastomers, tactiospecific C3+ .alpha.-olefins, intimate mixture thereof and the like.

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