Onium gallates cationic initiators

Details Onium gallates cationic initiators Onium gallates cationic initiators

1999-08-17

2000-12-26

Nazario-Gonzalez, Porfirio

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 28, 522 25, 522 29, C07F 500, C08F 246

Patent

active

06166233&

ABSTRACT:
The present invention relates to novel onium gallates or gallates of organometallic compounds and polymerizable compositions containing the same. The onium gallates include an anionic gallate moiety and a cationic moiety. The anionic gallate moiety has the formula

REFERENCES:
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Eaton, "Dye Sensitized Photopolymerization", Advances in Photochemistry, vol. 13, pp. 427-487 (1986) John Wiley & Sons.
Chatterjee et al., "Electron-Transfer Reactions in Cyanin Borate Ion Pairs: Photopolymerization Initiators Sensitive to Visible Light", J. Am. Chem. Soc., vol. 110, pp. 2326-2329 (1988).
Hassoon et al., "Electron Transfer Photoreduction of 5,7-Diiodo-3-butoxy-6-fluorone with Tetrabutylammonium Triphenylbutylborate and N,N-Dimenthyl-2,6-diisopropylaniline", J. Phys. Chem., 99, pp. 9416-9424 (1995).

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