One step preparation of linear antioxidant phenolic polymers inv

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 47R, 260 47UA, C08G 6540, C08F 452

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active

039961982

ABSTRACT:
Phenolic polymers having 3 to 1000 repeating units of the general structural formula ##STR1## wherein X and X.sup.1 independently are hydrogens or methyls, R is a lower alkyl of from 1 to 6 carbon atoms or an aryl, alkaryl or aralkyl of from 6 to 14 carbon atoms, and R.sup.1, R.sup.2 and R.sup.3 independently are hydrogen, lower alkyls of from 1 to 6 carbon atoms, aralkyls of from 8 to 14 carbons, or alkoxys or aralkyloxys of from 1 to about 14 carbons, are prepared in one step by contacting an R.sup.1, R.sup.2 and R.sup.3 -containing phenol having two hydrogens ortho to the hydroxyl group with a low purity diolefinic hydrocarbon under ortho-alkylation conditions in the presence of an effective amount of an ortho-alkylation catalyst. These materials find use as antioxidants, especially for edibles, where their polymeric nature offers advantages.

REFERENCES:
patent: 2224837 (1940-12-01), Rosenthal et al.
patent: 2665312 (1954-01-01), Ohlmann
patent: 3004953 (1961-10-01), Sonnabend
patent: 3420915 (1969-01-01), Braithwaite, Jr.
patent: 3546173 (1970-12-01), Hunt
patent: 3733365 (1973-05-01), Yeakey et al.

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