Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...
Patent
1989-10-19
1991-06-18
Marquis, Melvyn I.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From silicon reactant having at least one...
528 31, 528 32, 525478, C08G 7706
Patent
active
050250736
ABSTRACT:
Shelf stable heat curable mixtures of vinyl-substituted organopolysiloxane fluids and siloxanehydride are provided. These one part organopolysiloxane mixtures are catalyzed with an inclusion compound of a platinum metal complex, such as a complex of a platinum halide and 1,5-cyclooctadiene and a cyclodextrin.
REFERENCES:
A. Harada and S. Takahashi, Preparation and Properties of Inclusion Compounds to Transition Metal Complexes of Cyclo-octa-1,5-diene and Norbornadiene with Cyclodextrins. J. of Chem. Soc. No. 16, 1986.
A. Harada and S. Takahashi, Preparation and Properties of Cyclodextrin-Ferrocene Inclusion Complexes. J. of Chem. Soc. 1984.
A. Harada, Y.Hu, S. Yamamoto & S. Takahashi, Preparation and Properties of Inclusion Compounds of Ferrocene and its Derivatives and Cyclodextrins, J. Chem. Soc. Dalton Trans. 1988.
B. Nageshwer Rao, M. S. Syamala, N. J. Turro & V. Ramamurthy Modification of Photochemical Reactivity by Cyclodextrin Complexation: A Remarkable Effect on the Photobehavior of .alpha.-Alkyldibenzyl Ketones. J. Org. Chem. 1987, 52, 5517-5527.
H. C. Clark & L. E. Manzer, Reactions of (.pi.-1,5-Cyclooctadiene) Organoplatinum(II) Compounds and the Synthesis of Perfluoroalkylplatinum complexes, J. of Org. Chem. 59(1973) 411-428.
D. R. Alston, A. M. Z. Salwin, J. F. Stoddart, D. J. Williams & R. Zarzycki Second Sphere Coordination ADducts of Phosphane-Transition Metal Complexes with .beta.-Cyclodextrin and its Methylated Derivative Angew. Chem. Int. Ed. Engl. 27 (1988) No. 9.
D. R. Alston, A. M. X. Slawin, J. F. Stoddart & D. J. Williams, Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes-The X-Ray Crystal Structure of (Rh(cod)9CH.sub.3).sub.2. cyclodextrin(PF.sub.6).6H.sub.2 O-Angew Chem. Int. Ed. Engl. 24 1985.
Lewis Larry N.
Sumpter Chris A.
Davis Jr. James C.
General Electric Company
Marquis Melvyn I.
Pittman William H.
Teoli William A.
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