One package, moisture curable, organopolysiloxane compositions a

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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528 19, 528 34, 528901, C08L 4300

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active

043574432

ABSTRACT:
One package moisture curable organopolysiloxane compositions are provided based on the use of a silanol-terminated polydiorganosiloxane, an alkoxy silane crosslinking agent and a vanadium compound as a curing catalyst. The moisture curable organopolysiloxane compositions are non-corrosive and substantially odor-free.

REFERENCES:
patent: 3334066 (1967-08-01), Lamoreaux
patent: 3433758 (1969-03-01), Thomas
patent: 3457224 (1969-07-01), Thomas
Riechel et al., Electrochemical Studies of Vanadium (III)-(IV), and -(V) Compleses of 8-Quinolinol in Acetonitrile, Formation of Binuclear Mixed-Valence (IV, V) Complex, Inorg. Chem., vol. 14, No. 8, (1975), pp. 1869-1875.
Pasquali et al., (Pyridine)bis(8-quinolinato)oxovanadium (IV): A Free-Radical-Like Metal Center in Reactions with Dioxygen, p-Benzoquinone, and Aromatic Nitroso Compounds, Inorg. Chem., vol. 18, No. 9, (1979), pp. 2397-2400.
Pasquali et al., J.C.S. Dalton, (1977), pp. 139-144, Oxovanadium (IV) Complexes Containing Bidentate Schiff-base Ligands: Synthesis and Structural and Spectroscopic Data.
Cotton et al., Advanced Inorganic Chemistry, A Comprehensive Text., 4th Ed., (1980), John Wiley & Sons, Inc.

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