.omega.,.omega.-Diacyloxy-2,6-dimethyl-octatrienoates and -octat

Details .omega.,.omega.-Diacyloxy-2,6-dimethyl-octatrienoates and -octat .omega.,.omega.-Diacyloxy-2,6-dimethyl-octatrienoates and -octat

1983-11-28

1985-09-24

Love, Ethel G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

560190, 560205, 560262, C07D31906, C07C 6702

Patent

active

045434174

ABSTRACT:
.omega.,.omega.-Diacyloxy-2,6-dimethyl-octatrienoates and -octatrienals, as novel bifunctional asymmetric C.sub.10 building blocks for terpene syntheses, which possess a formyl or alkoxycarbonyl group at one chain end and 2 geminal acyloxy groups at the other, and a process for their preparation from readily obtainable industrial C.sub.5 building blocks and their use for the synthesis of terpene compounds by carbonyl olefination under conventional conditions.

REFERENCES:
patent: 3236879 (1966-02-01), Chuisoli
patent: 3634518 (1972-01-01), Buddrus
patent: 3989758 (1976-11-01), Ruegg et al.
patent: 4284796 (1981-08-01), Fischer et al.
patent: 4410719 (1983-10-01), Fischer et al.
Helv. Chim. Acta 69, 369, (1966).
J. Chem. Soc., 1965, 2019.
Chem. Ber. 107, 2050, (1974).
Org. Reactions, vol. 14, pp. 271-291, (1965).
Chem. Rev. 74, 87, (1974).

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