Oligomerizing alpha-olefins with a heterogeneous catalyst

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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252420, C07C 202

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active

043084141

ABSTRACT:
An alpha-olefin is oligomerized in the presence of a three-component catalyst comprising a particulate solid adsorbent having boron trifluoride and water adsorbed on the solid adsorbent. For example, 1-decene is oligomerized to a product predominating in the trimer and tetramer using silica as the solid adsorbent.

REFERENCES:
patent: 3109041 (1963-10-01), Child et al.
patent: 3190936 (1965-06-01), Child et al.
patent: 3997621 (1976-12-01), Brennen

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