Oligomerization to alpha-olefins

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585514, 585515, 585527, 502155, 502162, 502165, 502167, 502117, C07C 202, C07C 236

Patent

active

046894373

ABSTRACT:
An olefin oligomerization/cooligomerization process with a catalyst comprising the reaction product of (1) a transition metal compound selected from the metals Ni, Co, Cr, Fe, Cu, (2) a catalyst activator capable of donating a hydride, alkyl, alkenyl or aryl group when the transition metal has the oxidation state of O or the transition metal compound does not have a hydride, alkyl, alkenyl or aryl group, and (3a) an organophosphorus sulfonate ligand containing one benzene ring with trivalent phosphorus P(III) group and SO.sub.3 M group at ortho-positions, or one benzene ring with CH.sub.2 --P(III) and CH.sub.2 --SO.sub.3 M groups at ortho-positions, or a bridging or fused aromatic ring system with P(III) or CH.sub.2 --P(III) group and SO.sub.3 M or CH.sub.2 --SO.sub.3 M group at adjacent positions on different rings, or any aromatic ring having the P(III) and SO.sub.3 M groups at adjacent positions, where M is H, Group IA or Group IIA metals, quarternary ammonium or phosphonium (NR.sub.4, PR.sub.4) radical, or (3b) a P(III) component connected through

REFERENCES:
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patent: 4293727 (1981-10-01), Beach et al.
patent: 4310716 (1982-01-01), Beach et al.
patent: 4382153 (1983-05-01), Beach et al.
patent: 4487847 (1984-12-01), Knudsen

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