Olefine polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252429B, 526 77, 526139, 526357, 526906, C08F 476

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active

041828160

ABSTRACT:
A titanium trihalide is ground with an organic Lewis Base compound which contains at least one phosphorus atom, and optionally at least one nitrogen atom, and a titanium tetrahalide, the Lewis Base and the titanium tetrahalide being used in amounts of 5 to 75, preferably 5 to 50%, molar and 1 to 50, preferably 5 to 30% molar respectively relative to the titanium trihalide. The materials are conveniently milled together and the milled product can be used as a component of an olefine polymerization catalyst and when such catalysts are used to polymerize propylene a high activity is achieved together with satisfactory stereospecificity.

REFERENCES:
patent: 4051307 (1977-09-01), Caunt et al.

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