Olefin separation process

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.

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Details

585838, 585839, 585844, C07C 701

Patent

active

041743539

ABSTRACT:
There is disclosed a process for the separation of ethylene or propylene from a purified, multi-component gas stream produced from the thermal cracking of hydrocarbons and containing ethylene or propylene and other low molecular weight components comprising the steps of: introducing said multi-component gas stream into an aqueous silver salt solution stream to effect the absorption and/or complexing of said contained ethylene or propylene and reaction of trace acetylenes with the silver metal ions of such solution; venting of the silver salt solution stream at reduced pressure to remove the dissolved other low molecular weight components; treating the resulting silver salt solution stream to separate the absorbed and/or complexed ethylene or propylene from the silver salt stream; further treating the resultant silver salt solution stream to release the contained trace acetylenes therefrom and provide an aqueous silver salt stream; and recycling said aqueous silver salt stream to said introducing step.

REFERENCES:
patent: 2831907 (1958-04-01), Mayfield et al.
patent: 2913505 (1959-11-01), Van Raay et al.
patent: 3101381 (1963-08-01), Baxter
patent: 3189658 (1965-06-01), Quinn
patent: 3331190 (1967-07-01), Glew et al.
patent: 3395192 (1968-07-01), Long
patent: 3402212 (1968-09-01), Gantt

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