Olefin separation process

Mineral oils: processes and products – Fractionation – Adsorption

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260677AD, C10G 2504

Patent

active

039692230

ABSTRACT:
An improved process for the separation of olefins from a hydrocarbon feed mixture comprising olefins and saturates which process uses a zeolite adsorbent to selectively adsorb the olefins. The improvement comprises employing a zeolite adsorbent produced by the steps of: contacting a precursor mass containing type X structured zeolite and amorphous material as a binder with an aqueous caustic solution to effect the addition of alkali metal cations to the crystalline structure; washing the mass with water to remove therefrom excess caustic solution; and, at least partially dehydrating said mass at dehydrating conditions thereby producing an adsorbent which has both increased capacity for olefins and decreased catalytic activity.

REFERENCES:
patent: 3265750 (1966-08-01), Peck et al.
patent: 3326797 (1967-06-01), Young
patent: 3706813 (1972-12-01), Neuzil
patent: 3717572 (1973-02-01), Gramont et al.

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