Olefin polymerization process in the presence of a radical...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S348000, C526S160000, C526S943000, C526S124200, C526S124300, C526S219600

Reexamination Certificate

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07378476

ABSTRACT:
An olefin polymerization process comprises gas-phase polymerization of at least one olefin monomer in a reactor using a Ziegler-Natta or metallocene catalyst system in the presence of at least one suitable radical-generating compound in an amount sufficient for polymer modification and subsequent stabilization of such compound and generated radicals before post-reactor heat processing.

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Rätzsch et al., Radical reactions on polypropylene in the solid state, Prog. Polym. Sci., vol. 27, 2002, pp. 1195-1282.

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