Olefin polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526104, 526106, 526194, 526348, 526352, C08F 402, C08F 424, C08F 1002, C08F 1000

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active

039608263

ABSTRACT:
An olefin polymerization process for the preparation of polyolefins having relatively low molecular weights and high melt indexes without loss of catalyst activity, utilizing a catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which volume is provided by pores having pore diameters ranging from 300 to 600 A and a surface area ranging from 200 to 500 m.sup.2 /g, and having deposited thereon a metal-containing catalytic material, such as chromium oxide, or other metal oxide. The process is designed for the preparation of polymers and copolymers of 1-olefins having a maximum of 8 carbon atoms in the chain and having no branching nearer the double bond than the 4-position, e.g., ethylene polymers.

REFERENCES:
patent: 3225023 (1965-12-01), Hogan et al.
patent: 3819598 (1974-06-01), Galiano et al.

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